Issue 29, 2020

Interaction of carbon monoxide with doped metal clusters

Abstract

The interaction between carbon monoxide and metal-based catalysts is important in several reactions such as CO hydrogenation, CO oxidation, and CO2 reduction. Consequently, CO adsorption on metal surfaces and nanoparticles largely has been investigated. Current understanding of the microscopic mechanism that governs the metal–CO binding has been enhanced by gas phase studies of well-defined small metal cluster model systems as a function of their size, charge state, and composition. In this highlight paper, key experimental and computational studies dealing with the interaction between CO and transition and coinage metal clusters are discussed, with particular emphasis on the influence of dopant atoms.

Graphical abstract: Interaction of carbon monoxide with doped metal clusters

Article information

Article type
Highlight
Submitted
18 Mai 2020
Accepted
04 Jul 2020
First published
06 Jul 2020

CrystEngComm, 2020,22, 4807-4815

Interaction of carbon monoxide with doped metal clusters

P. Ferrari, G. Libeert, N. M. Tam and E. Janssens, CrystEngComm, 2020, 22, 4807 DOI: 10.1039/D0CE00733A

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