Issue 92, 2020

Characterization of heterogeneous aryl–Pd(ii)–oxo clusters as active species for C–H arylation

Abstract

C–H arylation with heterogeneous palladium was investigated. The surface oxidation of Pd nanoparticles with a hypervalent iodine reagent, [Ph2I]BF4, resulted in the generation of Pd(II)–aryl–oxo clusters, which were characterized as the crucial intermediate.

Graphical abstract: Characterization of heterogeneous aryl–Pd(ii)–oxo clusters as active species for C–H arylation

Supplementary files

Article information

Article type
Communication
Submitted
08 Okt 2020
Accepted
28 Okt 2020
First published
28 Okt 2020

Chem. Commun., 2020,56, 14404-14407

Characterization of heterogeneous aryl–Pd(II)–oxo clusters as active species for C–H arylation

T. Shin, M. Kim, Y. Jung, S. J. Cho, H. Kim and H. Song, Chem. Commun., 2020, 56, 14404 DOI: 10.1039/D0CC06716D

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