Preparation of polythiophene microrods with ordered chain alignment using nanoporous coordination template

Takashi Kitao; Michael W. A. MacLean; Benjamin Le Ouay; Yotaro Sasaki; Masahiko Tsujimoto; Susumu Kitagawa; Takashi Uemura

doi:10.1039/C7PY00309A

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Preparation of polythiophene microrods with ordered chain alignment using nanoporous coordination template†

Takashi Kitao,

^a Michael W. A. MacLean,^ab Benjamin Le Ouay,^ab Yotaro Sasaki,^a Masahiko Tsujimoto,^c Susumu Kitagawa^ac and Takashi Uemura

*^ab

Author affiliations

* Corresponding authors

^a Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan
E-mail: uemura@sbchem.kyoto-u.ac.jp

^b CREST, Japan Science and Technology Agency (JST), 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan

^c Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan

Abstract

The properties of polymeric materials can be amplified by macromolecular alignment. The highly ordered chain alignment of unsubstituted polythiophene, an unprocessable polymer, has been achieved using a porous coordination polymer (PCP) as a template. Due to the extended conjugation system, the obtained anisotropic polymer particles exhibit higher conductivity than that of polythiophene prepared by solution polymerization.

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Article information

DOI: https://doi.org/10.1039/C7PY00309A
Article type: Paper
Submitted: 23 Feb 2017
Accepted: 27 Mär 2017
First published: 27 Mär 2017

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Polym. Chem., 2017,8, 5077-5081

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Preparation of polythiophene microrods with ordered chain alignment using nanoporous coordination template

T. Kitao, M. W. A. MacLean, B. Le Ouay, Y. Sasaki, M. Tsujimoto, S. Kitagawa and T. Uemura, Polym. Chem., 2017, 8, 5077 DOI: 10.1039/C7PY00309A

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Polymer Chemistry

Preparation of polythiophene microrods with ordered chain alignment using nanoporous coordination template†

Abstract

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Preparation of polythiophene microrods with ordered chain alignment using nanoporous coordination template

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