Issue 28, 2016

Photoresponsive spiropyran-functionalised MOF-808: postsynthetic incorporation and light dependent gas adsorption properties

Abstract

The first example of a spiropyran-incorporated metal–organic framework was synthesised via a two-step post-synthesis modification of the Zr-oxo nodes in MOF-808. The incorporated spiropyran could not otherwise be obtained via the analogous one-step de novo synthesis. The resulting MOF-808-SP showed a photoresponsive surface area, pore volume and CO2 uptake, relevant for light-dependent gas separations processes.

Graphical abstract: Photoresponsive spiropyran-functionalised MOF-808: postsynthetic incorporation and light dependent gas adsorption properties

Supplementary files

Article information

Article type
Communication
Submitted
19 Mai 2016
Accepted
22 Jun 2016
First published
04 Jul 2016

J. Mater. Chem. A, 2016,4, 10816-10819

Photoresponsive spiropyran-functionalised MOF-808: postsynthetic incorporation and light dependent gas adsorption properties

K. Healey, W. Liang, P. D. Southon, T. L. Church and D. M. D'Alessandro, J. Mater. Chem. A, 2016, 4, 10816 DOI: 10.1039/C6TA04160D

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