Issue 6, 2014

Polythiophene synthesis via halogen dance

Abstract

Polymerization of 2,4-dibromo-3-hexyl-5-lithiated thiophene that is formed by deprotonation of 2,5-dibromo-3-hexylthiophene with LDA and following halogen dance takes place in the presence of a nickel(II) or palladium(II) catalyst to afford poly(3-bromo-4-hexylthiophen-2,5-diyl).

Graphical abstract: Polythiophene synthesis via halogen dance

Supplementary files

Article information

Article type
Research Article
Submitted
08 Apr 2014
Accepted
16 Mai 2014
First published
16 Mai 2014

Org. Chem. Front., 2014,1, 678-682

Author version available

Polythiophene synthesis via halogen dance

K. Shono, Y. Sumino, S. Tanaka, S. Tamba and A. Mori, Org. Chem. Front., 2014, 1, 678 DOI: 10.1039/C4QO00109E

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