Issue 47, 2009

Stereoselective gold-catalyzed cycloaddition of functionalized ketoenynes: synthesis of (+)-orientalol F

Abstract

A stereoselective gold-catalyzed [2 + 2 + 2] cycloaddition of ketoenynes substituted at the propargylic position with OR groups has been applied for the synthesis of (+)-orientalol F and pubinernoid B.

Graphical abstract: Stereoselective gold-catalyzed cycloaddition of functionalized ketoenynes: synthesis of (+)-orientalol F

Supplementary files

Article information

Article type
Communication
Submitted
28 Sep 2009
Accepted
19 Okt 2009
First published
05 Nov 2009

Chem. Commun., 2009, 7327-7329

Stereoselective gold-catalyzed cycloaddition of functionalized ketoenynes: synthesis of (+)-orientalol F

E. Jiménez-Núñez, K. Molawi and A. M. Echavarren, Chem. Commun., 2009, 7327 DOI: 10.1039/B920119J

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