Issue 38, 2009

Metal-catalyzed rearrangement of enantiomerically pure alkylidenecyclopropane derivatives as a new access to cyclobutenes possessing quaternary stereocenters

Abstract

Pd(II)- and Pt(II)-catalyzed ring-expansion of enantiomerically pure alkylidenecyclopropane derivatives leads to the formation of cyclobutene species with a complete preservation of the stereogenic center.

Graphical abstract: Metal-catalyzed rearrangement of enantiomerically pure alkylidenecyclopropane derivatives as a new access to cyclobutenes possessing quaternary stereocenters

Supplementary files

Article information

Article type
Communication
Submitted
28 Mai 2009
Accepted
07 Aug 2009
First published
02 Sep 2009

Chem. Commun., 2009, 5760-5762

Metal-catalyzed rearrangement of enantiomerically pure alkylidenecyclopropane derivatives as a new access to cyclobutenes possessing quaternary stereocenters

A. Masarwa, A. Fürstner and I. Marek, Chem. Commun., 2009, 5760 DOI: 10.1039/B910465H

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