Issue 29, 2009

Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality

Abstract

Achiral meteoritic amino acids, glycine and α-methylalanine, with hydrogen isotope (D/H) chirality, acted as the source of chirality in asymmetric autocatalysis with amplification of ee to afford highly enantioenriched 5-pyrimidyl alkanols.

Graphical abstract: Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality

Supplementary files

Article information

Article type
Communication
Submitted
05 Mai 2009
Accepted
08 Jun 2009
First published
24 Jun 2009
This article is Open Access

Chem. Commun., 2009, 4396-4398

Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality

T. Kawasaki, M. Shimizu, D. Nishiyama, M. Ito, H. Ozawa and K. Soai, Chem. Commun., 2009, 4396 DOI: 10.1039/B908754K

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