Issue 29, 2017
From the journal:

CrystEngComm

An in situ investigation of the water-induced phase transformation of UTSA-74 to MOF-74(Zn)†

Bart Bueken,a   Helge Reinsch, ORCID logo b   Niclas Heidenreich,b   Annelies Vandekerkhove,a   Frederik Vermoortele,a   Christine E. A. Kirschhock,a   Norbert Stock, ORCID logo b   Dirk De Vosa  and  Rob Ameloot ORCID logo *a  

* Corresponding authors

a Centre for Surface Chemistry and Catalysis, Department M2S, KU Leuven, Celestijnenlaan 200F p.o. box 2461, 3001 Leuven, Belgium
E-mail: rob.ameloot@kuleuven.be

b Institut für Anorganische Chemie, Christian-Albrechts Universität zu Kiel, Max-Eyth Straße 2, D-24118 Kiel, Germany

Abstract

We report the water-induced transformation of the [Zn2(dobdc)] (dobdc = 2,5-dioxidobenzene-1,4-dicarboxylate) metal–organic framework UTSA-74 to its polymorph MOF-74(Zn), contrary to a previous report on the stability of UTSA-74 under such conditions. This dissolution–recrystallization process was investigated using time-resolved in situ X-ray diffraction and kinetically analyzed using the Gualtieri crystallization model.

Graphical abstract: An in situ investigation of the water-induced phase transformation of UTSA-74 to MOF-74(Zn)

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C7CE00094D
Article type
Communication
Submitted
13 Jan 2017
Accepted
17 Feb 2017
First published
20 Feb 2017

CrystEngComm, 2017,19, 4152-4156

Permissions

Request permissions

An in situ investigation of the water-induced phase transformation of UTSA-74 to MOF-74(Zn)

B. Bueken, H. Reinsch, N. Heidenreich, A. Vandekerkhove, F. Vermoortele, C. E. A. Kirschhock, N. Stock, D. De Vos and R. Ameloot, CrystEngComm, 2017, 19, 4152 DOI: 10.1039/C7CE00094D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements