Issue 24, 2016

Electrophilic activation of alkynes for enyne cycloisomerization reactions with in situ generated early/late heterobimetallic Pt–Ti catalysts

Abstract

In situ formation of heterobimetallic Pt–Ti catalysts enables rapid room temperature catalysis in enyne cycloisomerization reactions. The Lewis acidic titanium atom in the ligand framework is shown to be essential for fast catalysis. A range of enyne substrates are efficiently cyclized to carbocycles and heterocycles in high yield.

Graphical abstract: Electrophilic activation of alkynes for enyne cycloisomerization reactions with in situ generated early/late heterobimetallic Pt–Ti catalysts

Supplementary files

Article information

Article type
Communication
Submitted
07 Mai 2016
Accepted
18 Mai 2016
First published
20 Mai 2016

Dalton Trans., 2016,45, 9770-9773

Electrophilic activation of alkynes for enyne cycloisomerization reactions with in situ generated early/late heterobimetallic Pt–Ti catalysts

M. R. Talley, R. W. Stokes, W. K. Walker and D. J. Michaelis, Dalton Trans., 2016, 45, 9770 DOI: 10.1039/C6DT01783E

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