Karthika U. V., Mohan Neetha and Gopinathan Anilkumar
Org. Biomol. Chem., 2025,23, 9079-9093
Abstract
This review highlights recent advances in copper-catalyzed thiocyanation, showcasing copper’s versatility, cost-effectiveness, and efficiency in introducing the SCN− group into diverse organic substrates, thereby enabling the synthesis of sulfur-containing compounds vital to pharmaceuticals and natural products.
Arun Yadav, Sabhya Sandha and Chandra Bhushan Tripathi
Chem. Commun., 2023,59, 5579-5582
Abstract
A Brønsted acid-catalyzed photoinduced intermolecular alkylative isothiocyanation of conjugated dienes is reported. The optimized method does not require any exogenous photocatalyst or additives.
Bumpei Maeda and Kei Murakami
Chem. Commun., 2024,60, 2839-2864
Abstract
Isothiocyanates exhibit diverse bioactivities and reactivities. This review describes a comprehensive summary of recent advances in isothiocyanate synthesis with a focus on substrate categorization.
Shixuan Jiang, Daijiao Zhuang, Peihua Liu, Qiyang Xu, Xiaofeng Luo, Tianqiang Wang, Chengcheng Zhang and Rulong Yan
Org. Biomol. Chem., 2024,22, 4472-4477
Abstract
A metal-free method to synthesize diversely substituted isothiocyanato alkyl sulfides with KSCN and DMTSM has been developed through the formation of C–NCS and C–S bonds.
Xinyu Pang, Hui He, Xiangrui Meng, Linbao Zhang, Shaofei Ni, Ming Li and Weisi Guo
Org. Chem. Front., 2024,11, 2283-2288
Abstract
An electrochemical thiocyanation of distal C(sp3)–H bonds based on amidyl radical-mediated 1,5-HAT has been developed. The transformation is highly site-selective and compatible with primary, secondary, and tertiary sulfonamides, and bioactive derivatives.