This review highlights the advances from the past decade that provide readers with essential tools for designing and implementing radical sulfonylation using SO2 surrogates in organic synthesis.
Direct functionalization of unactivated alkenes via visible-light photocatalysis has emerged as a highly effective strategy for the rapid construction of multi-functional, complex molecular architectures from simple, abundant chemicals.
Recent advances in the photochemistry of EDA complexes: a practical and modern strategy for efficient carbon–sulfur bond formation in organic synthesis.
This review comprehensively summarizes the dichalcogenative functionalization of unsaturated compounds over the past decade. The scopes, limitations and detailed reaction mechanisms are also discussed.
We highlighted the applications of sulfonyl hydrazides in radical cyclization of alkenes, which generally has two radical conversion modes, including sulfonyl radicals and sulfoxide radicals, with an emphasis on their reaction mechanisms.