Xiting Yuan, Zichen Ye, Sami Malola, Osama Shekhah, Hao Jiang, Xinyan Hu, Jian-Xin Wang, Hong Wang, Aleksander Shkurenko, Jiangtao Jia, Vincent Guillerm, Omar F. Mohammed, Xiaolan Chen, Nanfeng Zheng, Hannu Häkkinen and Mohamed Eddaoudi

Chem. Sci., 2024, 15, 16112
DOI: 10.1039/D4SC04594G

A thermostable terbium(iii) complex with high fluorescence quantum yields

Bao-Li Chen, Yan-Mei Sun, Hua Xiang, Mu-Xiong Lin, Jian-Han Li and Yong-Liang Huang

New J. Chem., 2022, 46, 11021
DOI: 10.1039/D2NJ01250B

Tailoring two magic number Au13 nanoclusters with N-containing diphosphine ligands: a classical icosahedral core vs. an unprecedented UFO- shaped core

Jing Liu, Jia-Chuan Liu, Hai-Ling Wang, Pei-Yu Liao, Jian-Hua Jia and Ming-Liang Tong

Inorg. Chem. Front., 2024, 11, 2553
DOI: 10.1039/D4QI00334A

Novel dinuclear NHC–gold(i)-amido complexes and their application in energy transfer photocatalysis

Xinyuan Ma, Vladislav A. Voloshkin, Ekaterina A. Martynova, Marek Beliš, Min Peng, Marco Villa, Nikolaos V. Tzouras, Wim Janssens, Kristof Van Hecke, Paola Ceroni and Steven P. Nolan

Catal. Sci. Technol., 2023, 13, 4168
DOI: 10.1039/D3CY00716B

An insight, at the atomic level, into the structure and catalytic properties of the isomers of the Cu22 cluster

Huimin Zhou, Tao Yang, Huijuan Deng, Yapei Yun, Shan Jin, Lin Xiong and Manzhou Zhu

Nanoscale, 2024, 16, 10318
DOI: 10.1039/D4NR00973H

Monoarsine-protected icosahedral cluster [Au13(AsPh3)8Cl4]+: comparative studies on ligand effect and surface reactivity with its stibine analogue

Jiu-Hong Yu, Zhi-Rui Yuan, Jing Xu, Jin-Gui Wang, Mohammad Azam, Tian-Duo Li, Ying-Zhou Li and Di Sun

Chem. Sci., 2023, 14, 6564
DOI: 10.1039/D3SC01311A

Tuning photoluminescence properties of Au clusters by surface modification and doping: lessons from case studies of icosahedral Au13

Dennis Alexander Buschmann, Haru Hirai and Tatsuya Tsukuda

Inorg. Chem. Front., 2024, 11, 6694
DOI: 10.1039/D4QI01773K

Liquid crystal-mediated self-assembly of copper nanoclusters with induced circular dichroism and amplified circularly polarized luminescence

Shulin Li, Ning Feng, Mengdi Sun, Yuxiang Sha, Xia Xin, Hui Zhao and Hongguang Li

Nanoscale, 2024, 16, 18998
DOI: 10.1039/D4NR03125C

Overall structure of Au12Ag60(S-c-C6H11)31Br9(Dppp)6: achieving a stronger assembly of icosahedral M13units

Manman Zhou, Kang Li, Pu Wang, Huimin Zhou, Shan Jin, Yong Pei and Manzhou Zhu

Nanoscale, 2023, 15, 2633
DOI: 10.1039/D2NR06613K

Bright near-infrared circularly polarized electrochemiluminescence from Au9Ag4nanoclusters

Lirong Jiang, Mengmeng Jing, Bing Yin, Wenjun Du, Xiaojian Wang, Ying Liu, Shuang Chen and Manzhou Zhu

Chem. Sci., 2023, 14, 7304
DOI: 10.1039/D3SC01329D

Construction of an Au12Cd2 nanocluster with circularly polarized luminescence by a metal- and ligand-exchange strategy

Jun Zhou, Xiaofei Yang, Peisen Zheng, Qinzhen Li, Xiaowu Li, Jinsong Chai, Baoyu Huang, Sha Yang and Manzhou Zhu

Chem. Sci., 2024, 15, 4853
DOI: 10.1039/D3SC06810B

Glacial acetic acid as a resolution solvent for growing enantiopure crystals from racemic mixtures

Hongwen Deng, Peng Yuan, Kejie Lao, Qijun Fu, Boon K. Teo and Nanfeng Zheng

Inorg. Chem. Front., 2025, 12, 171
DOI: 10.1039/D4QI01944J

Tuning the surface chemistry of NHC-protected Au13 nanoclusters via a robust amide coupling procedure

Andrew L. D. M. Laluk, Dennis A. Buschmann, Shinjiro Takano, Angus I. Sullivan, Parimah Aminfar, Kevin Stamplecoskie, Tatsuya Tsukuda and Cathleen M. Crudden

Chem. Sci., 2025
DOI: 10.1039/D5SC02951A

Insights into the synthesis of NHC-stabilized Au nanoclusters through real-time reaction monitoring

Junliang Liu, Yusuke Sato, Viveka K. Kulkarni, Angus I. Sullivan, Wenyu Zhang, Cathleen M. Crudden and Jason E. Hein

Chem. Sci., 2023, 14, 10500
DOI: 10.1039/D3SC02077K

Highly Efficient Circularly Polarized Luminescence from Chiral Au13 Clusters Stabilized by Enantiopure Monodentate NHC Ligands

Peng Luo, Xue‐Jing Zhai, Sha Bai, Yu‐Bing Si, Xi‐Yan Dong, Ying‐Feng Han and Shuang‐Quan Zang

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202219017

Secondary ligand engineering of nanoclusters: Effects on molecular structures, supramolecular aggregates, and optical properties

Xiao Wei, Ying Lv, Honglei Shen, Hao Li, Xi Kang, Haizhu Yu and Manzhou Zhu

Aggregate, 2023, 4
DOI: 10.1002/agt2.246

NHC-Stabilized Au10 Nanoclusters and Their Conversion to Au25 Nanoclusters

Paul A. Lummis, Kimberly M. Osten, Tetyana I. Levchenko, Maryam Sabooni Asre Hazer, Sami Malola, Bryan Owens-Baird, Alex J. Veinot, Emily L. Albright, Gabriele Schatte, Shinjiro Takano, Kirill Kovnir, Kevin G. Stamplecoskie, Tatsuya Tsukuda, Hannu Häkkinen, Masakazu Nambo and Cathleen M. Crudden

JACS Au, 2022, 2, 875
DOI: 10.1021/jacsau.2c00004

Diving into Unknown Waters: Water-Soluble Clickable Au13 Nanoclusters Protected with N-Heterocyclic Carbenes for Bio-Medical Applications

Angus I. Sullivan, Emily A. Steele, Shinjiro Takano, Elham Zeinizade, Juan Chen, Sami Malola, Kumar Siddhant, Hannu Häkkinen, Kevin G. Stamplecoskie, Tatsuya Tsukuda, Gang Zheng and Cathleen M. Crudden

J. Am. Chem. Soc., 2025, 147, 4230
DOI: 10.1021/jacs.4c14240

Synthesis and Characterization of Enantiopure Chiral Bis NHC-Stabilized Edge-Shared Au10 Nanocluster with Unique Prolate Shape

Renee W. Y. Man, Hong Yi, Sami Malola, Shinjiro Takano, Tatsuya Tsukuda, Hannu Häkkinen, Masakazu Nambo and Cathleen M. Crudden

J. Am. Chem. Soc., 2022, 144, 2056
DOI: 10.1021/jacs.1c11857

Recent Advances in Ligand Engineering for Gold Nanocluster Catalysis: Ligand Library, Ligand Effects and Strategies

Mengyue Wang, Yu Chen and Cen Tang

Chemistry An Asian Journal, 2023, 18
DOI: 10.1002/asia.202300463

Carbene-stabilized enantiopure heterometallic clusters featuring EQE of 20.8% in circularly-polarized OLED

Xiao-Hong Ma, Jing Li, Peng Luo, Jia-Hua Hu, Zhen Han, Xi-Yan Dong, Guohua Xie and Shuang-Quan Zang

Nat Commun, 2023, 14
DOI: 10.1038/s41467-023-39802-w

Optical properties of gold nanoclusters constructed from Au13 units

Jie Kong, Wei Zhang, Yanzhen Wu and Meng Zhou

Aggregate, 2022, 3
DOI: 10.1002/agt2.207

Nanohybrids of atomically precise metal nanoclusters

Koustav Sahoo, Tapu Raihan Gazi, Soumyadip Roy and Indranath Chakraborty

Commun Chem, 2023, 6
DOI: 10.1038/s42004-023-00958-7

Ligand-Induced Cuboctahedral versus Icosahedral Core Isomerism within Eight-Electron Heterocyclic-Carbene-Protected Gold Nanoclusters

Jianyu Wei, Samia Kahlal, Jean-François Halet, Alvaro Muñoz-Castro and Jean-Yves Saillard

Inorg. Chem., 2022, 61, 8623
DOI: 10.1021/acs.inorgchem.2c01022

Gold(I)‐N‐Heterocyclic Carbene Synthons in Organometallic Synthesis

Thomas Scattolin, Giovanni Tonon, Eleonora Botter, Sebastien G. Guillet, Nikolaos V. Tzouras and Steven P. Nolan

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202301961

N-Heterocyclic Carbene-Stabilized Atomically Precise Metal Nanoclusters

Emily L. Albright, Tetyana I. Levchenko, Viveka K. Kulkarni, Angus I. Sullivan, Joseph F. DeJesus, Sami Malola, Shinjiro Takano, Masakazu Nambo, Kevin Stamplecoskie, Hannu Häkkinen, Tatsuya Tsukuda and Cathleen M. Crudden

J. Am. Chem. Soc., 2024, 146, 5759
DOI: 10.1021/jacs.3c11031

Highly Ordered N-Heterocyclic Carbene Monolayers on Cu(111)

Eloise Angove, Federico Grillo, Herbert A. Früchtl, Alex J. Veinot, Ishwar Singh, J. Hugh Horton, Cathleen M. Crudden and Christopher J. Baddeley

J. Phys. Chem. Lett., 2022, 13, 2051
DOI: 10.1021/acs.jpclett.1c04073

Electrocatalytic CO2 Reduction with Atomically Precise Au13 Nanoclusters: Effect of Ligand Shell on Catalytic Performance

Tetyana I. Levchenko, Hong Yi, Mark D. Aloisio, Ngoc Kim Dang, Guorui Gao, Shriya Sharma, Cao-Thang Dinh and Cathleen M. Crudden

ACS Catal., 2024, 14, 4155
DOI: 10.1021/acscatal.3c06114

Effect of Group-10 Element M (Ni, Pd, Pt) on Electronic Structure of Icosahedral M@Au12 Cores of MAu24L18 (L = Alkynyl, Thiolate)

Shinjiro Takano, Emi Ito, Toshikazu Nakamura and Tatsuya Tsukuda

J. Phys. Chem. C, 2023, 127, 4360
DOI: 10.1021/acs.jpcc.2c09037

N-Heterocyclic Carbene-Stabilized Hydrido Au24 Nanoclusters: Synthesis, Structure, and Electrocatalytic Reduction of CO2

Viveka K. Kulkarni, Behnam Nourmohammadi Khiarak, Shinjiro Takano, Sami Malola, Emily L. Albright, Tetyana I. Levchenko, Mark D. Aloisio, Cao-Thang Dinh, Tatsuya Tsukuda, Hannu Häkkinen and Cathleen M. Crudden

J. Am. Chem. Soc., 2022, 144, 9000
DOI: 10.1021/jacs.2c00789

Chiral Alkynyl‐Stabilized Ag/Cu Nanoclusters from Spontaneous Resolution

Xueli Sun, Zipeng Guo, Xiongkai Tang, Zhen Xu, Jing Sun, Zhenlang Xie, Zi‐Ang Nan, Shuo Guo and Hui Shen

ChemNanoMat, 2023, 9
DOI: 10.1002/cnma.202200514

Precise Surface Engineering of Metal Nanoclusters: Ligand Programming for Functionality Design

Zhucheng Yang, Yifan Wang, Ruixuan Zhang, Tiankai Chen and Jianping Xie

Advanced Materials, 2025
DOI: 10.1002/adma.202508578

Highly Luminescent NHC-Stabilized Au13 Clusters as Efficient Excited-State Electron Donors

Xiaotong Wang, Rong Liu, Limei Tian, Jingwen Bao, Chunyi Zhao, Fushuang Niu, Dajiao Cheng, Zhou Lu and Ke Hu

J. Phys. Chem. C, 2022, 126, 18374
DOI: 10.1021/acs.jpcc.2c06370

Filling the gaps in icosahedral superatomic metal clusters

Wei-Miao He, Jia-Hua Hu, Yu-Jia Cui, Jing Li, Yu-Bing Si, Shuai-Bo Wang, Yu-Jing Zhao, Zhan Zhou, Lu-Fang Ma and Shuang-Quan Zang

National Science Review, 2024, 11
DOI: 10.1093/nsr/nwae174

Generation and manipulation of chiroptical activities in coinage-metal clusters

Jia-Hong Huang, Xi-Yan Dong, Ya-Jie Wang and Shuang-Quan Zang

Coordination Chemistry Reviews, 2022, 470, 214729
DOI: 10.1016/j.ccr.2022.214729

Structural Control and Chiroptical Response in Intrinsically Tetra- and Pentanuclear Chiral Gold Clusters

Jian Tang and Liang Zhao

Inorg. Chem., 2022, 61, 4541
DOI: 10.1021/acs.inorgchem.2c00256

Highly Efficient Circularly Polarized Luminescence from Chiral Au13 Clusters Stabilized by Enantiopure Monodentate NHC Ligands

Peng Luo, Xue‐Jing Zhai, Sha Bai, Yu‐Bing Si, Xi‐Yan Dong, Ying‐Feng Han and Shuang‐Quan Zang

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202219017

N-heterocyclic carbene coordinated metal nanoparticles and nanoclusters

Hui Shen, Guolong Tian, Zhen Xu, Lingzheng Wang, Qingyuan Wu, Yuhao Zhang, Boon K. Teo and Nanfeng Zheng

Coordination Chemistry Reviews, 2022, 458, 214425
DOI: 10.1016/j.ccr.2022.214425

Atomic Precise Gold Nanoclusters: Toward the Customize Synthesis, Precision Medicine

Haile Liu, Lihui Wang, Zhonghua Xue and Xiao‐Dong Zhang

Part & Part Syst Charact, 2023, 40
DOI: 10.1002/ppsc.202300084

First Evidence of Au‐CH3 Bonding in Superatomic Au13 Clusters

Matteo Bevilacqua, Marco Roverso, Sara Bogialli, Claudia Graiff and Andrea Biffis

Eur J Inorg Chem, 2024, 27
DOI: 10.1002/ejic.202400351

Enantiopure Chiral Au13 Nanoclusters Stabilized by Ditopic N-Heterocyclic Carbenes: Synthesis, Characterization, and Electrocatalytic Reduction of CO2

Emily L. Albright, Sami Malola, Samuel I. Jacob, Hong Yi, Shinjiro Takano, Koichi Mimura, Tatsuya Tsukuda, Hannu Häkkinen, Masakazu Nambo and Cathleen M. Crudden

Chem. Mater., 2024, 36, 1279
DOI: 10.1021/acs.chemmater.3c02288

Symmetry breaking of highly symmetrical nanoclusters for triggering highly optical activity

Xiao Wei, Hao Li, Honglei Shen, Chuanjun Zhou, Shuxin Wang, Xi Kang and Manzhou Zhu

Fundamental Research, 2024, 4, 63
DOI: 10.1016/j.fmre.2022.03.007

Theory-Directed Ligand-Shell Engineering of Ultrasmall Gold Clusters: Remarkable Effects of Ligand Arrangement on Optical Properties

Rintaro Suzuki, Yuxiang Chen, Yuri Ogawa, Masaki Enokido, Yuichi Kitagawa, Yasuchika Hasegawa, Katsuaki Konishi and Yukatsu Shichibu

J. Phys. Chem. Lett., 2025, 16, 1432
DOI: 10.1021/acs.jpclett.4c03486

Synthesis and Characterization of a Monodentate N-Heterocyclic Carbene-Protected Au11-Nanocluster via Reduction with KC8

Angus I. Sullivan, Joseph F. DeJesus, Sami Malola, Shinjiro Takano, Tatsuya Tsukuda, Hannu Häkkinen and Cathleen M. Crudden

Chem. Mater., 2023, 35, 2790
DOI: 10.1021/acs.chemmater.2c03429

If the Crown Fits: Sterically Demanding N-Heterocyclic Carbene Promotes the Formation of Au8Pt Nanoclusters

Joseph F. DeJesus, Samuel I. Jacob, Quan Manh Phung, Koichi Mimura, Yoshitaka Aramaki, Takashi Ooi, Masakazu Nambo and Cathleen M. Crudden

J. Am. Chem. Soc., 2024, 146, 23806
DOI: 10.1021/jacs.4c04873

Controlling the Structure, Properties and Surface Reactivity of Clickable Azide‐Functionalized Au25(SR)18 Nanocluster Platforms Through Regioisomeric Ligand Modifications

Praveen N. Gunawardene, Julia Martin, Jonathan M. Wong, Zhifeng Ding, John F. Corrigan and Mark S. Workentin

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202205194

Coordination-Induced Trigger for Activity: N-Heterocyclic Carbene-Decorated Ceria Catalysts Incorporating Cr and Rh with Activity Induction by Surface Adsorption Site Control

Satoru Ikemoto, Satoshi Muratsugu, Takanori Koitaya, Yuta Tsuji, Mowpriya Das, Kazunari Yoshizawa, Frank Glorius and Mizuki Tada

J. Am. Chem. Soc., 2023, 145, 1497
DOI: 10.1021/jacs.2c07290

From Au11 to Au13: Tailored Synthesis of Superatomic Di-NHC/PPh3-Stabilized Molecular Gold Nanoclusters

Matteo Bevilacqua, Marco Roverso, Sara Bogialli, Claudia Graiff and Andrea Biffis

Inorg. Chem., 2023, 62, 1383
DOI: 10.1021/acs.inorgchem.2c03331

Controlling the Structure, Properties and Surface Reactivity of Clickable Azide‐Functionalized Au25(SR)18 Nanocluster Platforms Through Regioisomeric Ligand Modifications

Praveen N. Gunawardene, Julia Martin, Jonathan M. Wong, Zhifeng Ding, John F. Corrigan and Mark S. Workentin

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202205194

Significance of atomically precise copper nanoclusters and their alloys protected by organic monolayer in electrocatalytic carbon dioxide reduction reaction

Abdul Mannan Butt and Ahsanulhaq Qurashi

Coordination Chemistry Reviews, 2025, 541, 216823
DOI: 10.1016/j.ccr.2025.216823

Dipropyne‐Modified N‐Heterocyclic Carbene Stabilized Atomically Precise Copper(I) Nanocluster Catalysts for CO₂ Electroreduction

Bao‐Liang Han, Lan‐Cheng Zhao, Zhi‐Rui Yuan, Zhi Wang, Qun Yu, Geng‐Geng Luo, Li‐Kai Wang, Chen‐Ho Tung and Di Sun

Adv Funct Materials, 2025, 35
DOI: 10.1002/adfm.202500149

13C Chemical Shift of N-Heterocyclic Carbenes in Coinage Metal(I) Complexes and Clusters: trans-Influence and Spin–Orbit Coupling

Shahar Dery, Christian Ehinger, Jeremy Roudin, Yuya Kakiuchi, Domenico Gioffrè and Christophe Copéret

J. Am. Chem. Soc., 2025, 147, 18054
DOI: 10.1021/jacs.5c03929

Asymmetric Twisting of C-Centered Octahedral Gold(I) Clusters by Chiral N-Heterocyclic Carbene Ligation

Xiao-Li Pei, Pei Zhao, Hitoshi Ube, Zhen Lei, Koichi Nagata, Masahiro Ehara and Mitsuhiko Shionoya

J. Am. Chem. Soc., 2022, 144, 2156
DOI: 10.1021/jacs.1c10450

DFT Insights into the Variety in the Coordination Modes of the Equatorial Halides in [Au13Ag12(PR3)10X8]+ (X=Cl/Br) Clusters

Xiaohang Wu, Shiyin Weng, Ying Lv, Shuping He and Haizhu Yu

ChemPhysChem, 2023, 24
DOI: 10.1002/cphc.202200526

Anti-Heavy-Atom Effect Observed in Near-Infrared Emissive Bimetallic Nanoclusters Au28Cu12X4Cl4 (X = Cl, Br, and I)

Feng Hu, Zhen-Chao Long, Fangming Zhao, Wan-Qi Shi, Meng Zhou and Quan-Ming Wang

J. Am. Chem. Soc., 2025, 147, 19886
DOI: 10.1021/jacs.5c04083

Achiral-Core-Metal Change in Isomorphic Enantiomeric Ag12Ag32 and Au12Ag32 Clusters Triggers Circularly Polarized Phosphorescence

Yu-Jin Kong, Jia-Hua Hu, Xi-Yan Dong, Yubing Si, Zhao-Yang Wang, Xi-Ming Luo, Hong-Ren Li, Zongwei Chen, Shuang-Quan Zang and Thomas C. W. Mak

J. Am. Chem. Soc., 2022, 144, 19739
DOI: 10.1021/jacs.2c05881

Guiding the High-Yield Synthesis of NHC-Ligated Gold Nanoclusters by 19F NMR Spectroscopy

Hui Shen, Xiongkai Tang, Qingyuan Wu, Yuhao Zhang, Chuxin Ma, Zhen Xu, Boon K. Teo and Nanfeng Zheng

ACS Nanosci. Au, 2022, 2, 520
DOI: 10.1021/acsnanoscienceau.2c00026

Impact of Ligand Structure on Biological Activity and Photophysical Properties of NHC-Protected Au13 Nanoclusters

Viveka K. Kulkarni, Emily L. Albright, Elham Zeinizade, Emily Steele, Juan Chen, Lili Ding, Sami Malola, Shinjiro Takano, Kristen Harrington, Nahyun Kwon, Tetyana I. Levchenko, Masakazu Nambo, Tatsuya Tsukuda, Hannu Häkkinen, Kevin Stamplecoskie, Gang Zheng and Cathleen M. Crudden

J. Am. Chem. Soc., 2025, 147, 4017
DOI: 10.1021/jacs.4c12072

Development of an AMBER-Compatible Force Field for Gold Nanoclusters Protected by N-Heterocyclic Carbenes

María Francisca Matus, Maryam Sabooni Asre Hazer, Sami Malola and Hannu Häkkinen

J. Chem. Theory Comput., 2025
DOI: 10.1021/acs.jctc.5c00945

Synthesis and Vibrational Circular Dichroism Analysis of N-Heterocyclic Carbene Precursors Containing Remote Chirality Centers

Zita Szabó, Attila Paczal, Tibor Kovács, Attila Mándi, Andras Kotschy and Tibor Kurtán

IJMS, 2022, 23, 3471
DOI: 10.3390/ijms23073471

Atomically precise thiolate‐protected gold nanoclusters: Current status of designability of the structure and physicochemical properties

Sakiat Hossain, Daisuke Hirayama, Ayaka Ikeda, Mai Ishimi, Sota Funaki, Arpan Samanta, Tokuhisa Kawawaki and Yuichi Negishi

Aggregate, 2023, 4
DOI: 10.1002/agt2.255

Luminescence modulation of ultrasmall gold clusters by aromatic ligands

Xue-Jing Zhai, Jia-Hua Hu, Jianxin Guan, Yubing Si, Xi-Yan Dong, Peng Luo, Fangfang Pan, Zhihao Yu, Runping Han and Shuang-Quan Zang

Nano Res., 2023, 16, 11366
DOI: 10.1007/s12274-023-5817-5

Strategies for the enhancement of CPL properties

Madiha Saqlain, Hafiz Muhammad Zohaib, Samina Qamar, Hinna Malik and Hui Li

Coordination Chemistry Reviews, 2024, 501, 215559
DOI: 10.1016/j.ccr.2023.215559