Issue 15, 2021

Pb2.28Ba1.72B10O19 featuring a three-dimensional B–O anionic network with edge-sharing [BO4] obtained under ambient pressure

Abstract

The first borate featuring a three-dimensional B–O anionic network with edge-sharing (ES) [BO4] units, Pb2.28Ba1.72B10O19 (PbBaBO), has been synthesized under ambient pressure. The squeezing effect of the 2[B10O19] bilayer structure on the intra-layer co-edge [BO4] leads to an extremely long B–B distance and quite small internal O–B–O angles in the [B2O6] ring.

Graphical abstract: Pb2.28Ba1.72B10O19 featuring a three-dimensional B–O anionic network with edge-sharing [BO4] obtained under ambient pressure

Supplementary files

Article information

Article type
Research Article
Submitted
21 Mai 2021
Accepted
14 Jun 2021
First published
14 Jun 2021

Inorg. Chem. Front., 2021,8, 3716-3722

Pb2.28Ba1.72B10O19 featuring a three-dimensional B–O anionic network with edge-sharing [BO4] obtained under ambient pressure

S. Guo, W. Zhang, R. Yang, M. Zhang, Z. Yang and S. Pan, Inorg. Chem. Front., 2021, 8, 3716 DOI: 10.1039/D1QI00653C

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