Issue 12, 2011
From the journal:

Chemical Communications

Concerted halogen and hydrogen bonding in [RuI2(H2dcbpy)(CO)2]⋯I2⋯(CH3OH)⋯I2⋯[RuI2(H2dcbpy)(CO)2]†

Matti Tuikka,a   Mika Niskanen,a   Pipsa Hirva,a   Kari Rissanen,b   Arto Valkonenb  and  Matti Haukka*a  

* Corresponding authors

a Department of Chemistry, University of Eastern Finland, P.O. Box 111, FI-80101 Joensuu, Finland
E-mail: matti.haukka@uef.fi

b Department of Chemistry, Nanoscience Center, University of Jyväskylä, P.O. Box 35, FI-40014 University of Jyväskylä, Finland

Abstract

A new type of concerted halogen bond–hydrogen bond interaction was found in the solid state structure of [RuI2(H2dcbpy)(CO)2]⋯I2⋯(MeOH)⋯I2⋯[RuI2(H2dcbpy)(CO)2]. The iodine atoms of the two I2 molecules interact simultaneously with each other and with the OH group of methanol of crystallization. The interaction was characterized by single crystal X-ray measurements and by computational charge density analysis based on DFT calculations.

Graphical abstract: Concerted halogen and hydrogen bonding in [RuI2(H2dcbpy)(CO)2]⋯I2⋯(CH3OH)⋯I2⋯[RuI2(H2dcbpy)(CO)2]

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C0CC05726F
Article type
Communication
Submitted
22 Dez 2010
Accepted
13 Jän 2011
First published
02 Feb 2011

Chem. Commun., 2011,47, 3427-3429

Permissions

Request permissions

Concerted halogen and hydrogen bonding in [RuI2(H2dcbpy)(CO)2]⋯I2⋯(CH3OH)⋯I2⋯[RuI2(H2dcbpy)(CO)2]

M. Tuikka, M. Niskanen, P. Hirva, K. Rissanen, A. Valkonen and M. Haukka, Chem. Commun., 2011, 47, 3427 DOI: 10.1039/C0CC05726F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements