Cascade energy transfer augmented circular polarization in photofluorochromic cholesteric texture

Abstract

Circularly polarized luminescence (CPL)-active light-harvesting systems consisting of a light-responsive donor (R-1), mediator (Nile red), and terminal acceptor (Cyanine 5) are constructed in cholesteric liquid crystals. A dynamically tunable CPL dissymmetry factor and energy transfer modes, are achieved via the closed-ring and open-ring conversion between R-1-O and R-1-C.