Issue 5, 2021

Recent developments of nanocatalyzed liquid-phase hydrogen generation

Abstract

Hydrogen is the most effective and sustainable carrier of clean energy, and liquid-phase hydrogen storage materials with high hydrogen content, reversibility and good dehydrogenation kinetics are promising in view of “hydrogen economy”. Efficient, low-cost, safe and selective hydrogen generation from chemical storage materials remains challenging, however. In this Review article, an overview of the recent achievements is provided, addressing the topic of nanocatalysis of hydrogen production from liquid-phase hydrogen storage materials including metal-boron hydrides, borane–nitrogen compounds, and liquid organic hydrides. The state-of-the-art catalysts range from high-performance nanocatalysts based on noble and non-noble metal nanoparticles (NPs) to emerging single-atom catalysts. Key aspects that are discussed include insights into the dehydrogenation mechanisms, regenerations from the spent liquid chemical hydrides, and tandem reactions using the in situ generated hydrogen. Finally, challenges, perspectives, and research directions for this area are envisaged.

Graphical abstract: Recent developments of nanocatalyzed liquid-phase hydrogen generation

Article information

Article type
Review Article
Submitted
03 Okt 2020
First published
25 Jän 2021

Chem. Soc. Rev., 2021,50, 3437-3484

Recent developments of nanocatalyzed liquid-phase hydrogen generation

C. Wang and D. Astruc, Chem. Soc. Rev., 2021, 50, 3437 DOI: 10.1039/D0CS00515K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements