Issue 92, 2020
From the journal:

Chemical Communications

Characterization of heterogeneous aryl–Pd(ii)–oxo clusters as active species for C–H arylation†

Taeil Shin,‡a   Minjun Kim,‡a   Younjae Jung,a   Sung June Cho, ORCID logo *b   Hyunwoo Kim ORCID logo *a  and  Hyunjoon Song ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea
E-mail: hwkim@kaist.edu, hsong@kaist.ac.kr

b Department of Chemical Engineering, Chonnam National University, Gwangju 61186, Republic of Korea
E-mail: sjcho@chonnam.ac.kr

Abstract

C–H arylation with heterogeneous palladium was investigated. The surface oxidation of Pd nanoparticles with a hypervalent iodine reagent, [Ph2I]BF4, resulted in the generation of Pd(II)–aryl–oxo clusters, which were characterized as the crucial intermediate.

Graphical abstract: Characterization of heterogeneous aryl–Pd(ii)–oxo clusters as active species for C–H arylation

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Article information

DOI
https://doi.org/10.1039/D0CC06716D
Article type
Communication
Submitted
08 Okt 2020
Accepted
28 Okt 2020
First published
28 Okt 2020

Chem. Commun., 2020,56, 14404-14407

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Characterization of heterogeneous aryl–Pd(II)–oxo clusters as active species for C–H arylation

T. Shin, M. Kim, Y. Jung, S. J. Cho, H. Kim and H. Song, Chem. Commun., 2020, 56, 14404 DOI: 10.1039/D0CC06716D

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