Issue 10, 2019

Diffusion NMR for the characterization, in solution, of supramolecular systems based on calixarenes, resorcinarenes, and other macrocyclic arenes

Abstract

Diffusion NMR is a useful analytical tool for the characterization of supramolecular systems in solution. In this mini-review, after a short introduction and some methodological tips, we discuss, from a personal point of view, the use of diffusion NMR in the study of calixarene- and other arene-based supramolecular systems. We will demonstrate, through selected examples, how diffusion has been used to study, in solution, the structures and other characteristics of supramolecular systems based on calixarene and related systems ranging from different complexes and aggregates to molecular capsules and to supramolecular oligomers and polymers.

Graphical abstract: Diffusion NMR for the characterization, in solution, of supramolecular systems based on calixarenes, resorcinarenes, and other macrocyclic arenes

Article information

Article type
Review Article
Submitted
03 Mär 2019
Accepted
16 Apr 2019
First published
17 Apr 2019

Org. Chem. Front., 2019,6, 1705-1718

Diffusion NMR for the characterization, in solution, of supramolecular systems based on calixarenes, resorcinarenes, and other macrocyclic arenes

Y. Cohen and S. Slovak, Org. Chem. Front., 2019, 6, 1705 DOI: 10.1039/C9QO00329K

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