Using light to control the inhibition of Karstedt's catalyst†
Mitchell J.
Stashick 
a
and
Neil R.
Branda
*a
a
and
Neil R.
Branda
*a
Abstract
Hydrosilylation reactions are commonly used in the coating industry but the high activity of the platinum catalysts diminishes the ‘pot life’ of the reagents, and poses a serious industrial problem. In this communication, we illustrate a method for controlling the activity of these catalysts by using light as an external stimulant to turn ‘off’ a small molecule inhibitor, and activate the catalyst.
- This article is part of the themed collection: In celebration of Julius Rebek’s 75th Birthday
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