Tris(benzoimidazol)amine (L) complexes of pnictogen(III) and pnictogen(V) cations and assessment of the [LP]3+/[LPF2]3+ redox couple

Ala'aeddeen Swidan; Riccardo Suter; Charles L. B. Macdonald; Neil Burford

doi:10.1039/C8SC01682H

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Tris(benzoimidazol)amine (L) complexes of pnictogen(iii) and pnictogen(v) cations and assessment of the [LP]³⁺/[LPF₂]³⁺ redox couple†

Ala'aeddeen Swidan,

‡^a Riccardo Suter,

‡*^b Charles L. B. Macdonald

*^a and Neil Burford

*^b

Author affiliations

* Corresponding authors

^a Department of Chemistry and Biochemistry, University of Windsor, Windsor, Ontario N9B 3P4, Canada
E-mail: cmacd@uwindsor.ca

^b Department of Chemistry, University of Victoria, Victoria, British Columbia V8W 3V6, Canada
E-mail: nburford@uvic.ca, risuter@uvic.ca

Abstract

A series of cationic complexes involving a pnictogen(III) (Pn = P, As, Sb) centre and the tetradentate ligand tris((1-ethyl-benzoimidazol-2-yl)methyl)amine (BIMEt₃) have been synthesized and comprehensively characterized. Oxidation of [P(BIMEt₃)]³⁺ with XeF₂ provides access to [PF₂(BIMEt₃)]³⁺ representing the first structurally characterized example of a phosphorus(V) centred trication.

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Article information

DOI: https://doi.org/10.1039/C8SC01682H
Article type: Edge Article
Submitted: 13 Apr 2018
Accepted: 07 Jun 2018
First published: 19 Jun 2018
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry

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Chem. Sci., 2018,9, 5837-5841

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Tris(benzoimidazol)amine (L) complexes of pnictogen(III) and pnictogen(V) cations and assessment of the [LP]³⁺/[LPF₂]³⁺ redox couple

A. Swidan, R. Suter, C. L. B. Macdonald and N. Burford, Chem. Sci., 2018, 9, 5837 DOI: 10.1039/C8SC01682H

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