A solution-processable dissymmetric porous organic cage

A. G. Slater; M. A. Little; M. E. Briggs; K. E. Jelfs; A. I. Cooper

doi:10.1039/C7ME00090A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

A solution-processable dissymmetric porous organic cage†

A. G. Slater,

*^a M. A. Little,

^a M. E. Briggs,

^a K. E. Jelfs

^b and A. I. Cooper

Author affiliations

* Corresponding authors

^a Department of Chemistry and Materials Innovation Factory, University of Liverpool, Crown Street, Liverpool, UK
E-mail: anna.slater@liverpool.ac.uk

^b Department of Chemistry, Imperial College London, South Kensington, London SW7 2AZ, UK

Abstract

Two dissymmetric racemic analogues of the chiral porous organic cage, CC3, were isolated and unambiguously characterised as a racemate pair of the R,R,R,S,S,S and S,S,S,R,R,R-diastereomers (CC3-RS and CC3-SR). CC3-RS/CC3-SR equals the highest porosity measured for CC3 but is an order of magnitude more soluble, making it an excellent candidate for incorporation into a membrane for separation applications.

This article is part of the themed collections: In memory of Paul O’Brien, Celebrating Excellence in Research: 100 Women of Chemistry, 2018 MSDE Hot Articles and MSDE Emerging Investigators 2018

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C7ME00090A
Article type: Paper
Submitted: 04 Sep 2017
Accepted: 09 Okt 2017
First published: 22 Nov 2017
This article is Open Access

Download Citation

Mol. Syst. Des. Eng., 2018,3, 223-227

Permissions

Request permissions

A solution-processable dissymmetric porous organic cage

A. G. Slater, M. A. Little, M. E. Briggs, K. E. Jelfs and A. I. Cooper, Mol. Syst. Des. Eng., 2018, 3, 223 DOI: 10.1039/C7ME00090A

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Molecular Systems Design & Engineering

A solution-processable dissymmetric porous organic cage†

Abstract

Supplementary files

Article information

Download Citation

Permissions

A solution-processable dissymmetric porous organic cage

Social activity

Search articles by author

Spotlight

Advertisements