Issue 11, 2017
From the journal:

Journal of Materials Chemistry A

Charge transfer induced polymerization of EDOT confined between 2D titanium carbide layers†

Chi Chen,ab   Muhammad Boota,a   Xiuqiang Xie,ac   Mengqiang Zhao,a   Babak Anasori,a   Chang E. Ren,a   Ling Miao,b   Jianjun Jiang*b  and  Yury Gogotsi ORCID logo *a  

* Corresponding authors

a A. J. Drexel Nanomaterials Institute, Materials Science and Engineering Department, Drexel University, 3141 Chestnut Street, Philadelphia, PA 19104, USA
E-mail: gogotsi@drexel.edu

b School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan, Hubei 430074, People's Republic of China
E-mail: jiangjj@mail.hust.edu.cn

c Centre for Clean Energy Technology, School of Mathematical and Physical Sciences, University of Technology Sydney, Broadway, Sydney, NSW 2007, Australia

Abstract

In situ polymerization of 3,4-ethylenedioxythiophene (EDOT) is achieved on the surface of 2D Ti3C2Tx MXene without using any oxidant, resulting in improved lithium ion storage capability of Ti3C2Tx/poly-EDOT hybrids. A combined experimental and theoretical study revealed the mechanism of charge-transfer-induced polymerization of EDOT, which can be extended to other similar polymers.

Graphical abstract: Charge transfer induced polymerization of EDOT confined between 2D titanium carbide layers

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Article information

DOI
https://doi.org/10.1039/C7TA00149E
Article type
Communication
Submitted
05 Jän 2017
Accepted
15 Feb 2017
First published
15 Feb 2017

J. Mater. Chem. A, 2017,5, 5260-5265

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Charge transfer induced polymerization of EDOT confined between 2D titanium carbide layers

C. Chen, M. Boota, X. Xie, M. Zhao, B. Anasori, C. E. Ren, L. Miao, J. Jiang and Y. Gogotsi, J. Mater. Chem. A, 2017, 5, 5260 DOI: 10.1039/C7TA00149E

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