Issue 9, 2017
From the journal:

Organic Chemistry Frontiers

Identifying a cobalt catalyst for highly selective hydrosilylation of allenes†

Zheng Yang,‡ab   Dongjie Peng,‡ab   Xiaoyong Du,ab   Zheng Huang*ab  and  Shengming Ma ORCID logo *abc  

* Corresponding authors

a State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, P. R. China
E-mail: masm@sioc.ac.cn, huangzh@sioc.ac.cn

b University of Chinese Academy of Sciences, Beijing 100049, P. R. China

c Department of Chemistry, Fudan University, 220 Handan Lu, Shanghai 200433, P.R. China

Abstract

An efficient method of cobalt-catalyzed allene-hydrosilylation is developed. The reaction enjoys an excellent regio- and stereoselectivity and a broad scope affording Z-allylic silanes. Many synthetically useful functional groups can be tolerated. A Co(I)-species involved mechanism is proposed.

Graphical abstract: Identifying a cobalt catalyst for highly selective hydrosilylation of allenes

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Article information

DOI
https://doi.org/10.1039/C7QO00497D
Article type
Research Article
Submitted
21 Jun 2017
Accepted
16 Jul 2017
First published
18 Jul 2017
This article is Open Access
Creative Commons BY-NC license

Org. Chem. Front., 2017,4, 1829-1832

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Identifying a cobalt catalyst for highly selective hydrosilylation of allenes

Z. Yang, D. Peng, X. Du, Z. Huang and S. Ma, Org. Chem. Front., 2017, 4, 1829 DOI: 10.1039/C7QO00497D

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