Issue 4, 2015

Au(i) π-bis(tert-butyldimethylsilyl)acetylene triphenylphosphine complex, an effective pre-catalyst for Au(i)-catalyzed reactions

Abstract

A linear η2-alkyne π complex of [Ph3PAu]+, namely Au(I) π-bis(tert-butyldimethylsilyl)acetylene triphenylphosphine complex (1), was prepared and characterized. The new complex is found to be shelf-stable and effective for a range of the Au(I)-catalyzed alkyne π activation reactions, including a glycosylation reaction with glycosyl ortho-alkynylbenzoates as donors.

Graphical abstract: Au(i) π-bis(tert-butyldimethylsilyl)acetylene triphenylphosphine complex, an effective pre-catalyst for Au(i)-catalyzed reactions

Supplementary files

Article information

Article type
Research Article
Submitted
19 Jän 2015
Accepted
08 Feb 2015
First published
11 Feb 2015

Org. Chem. Front., 2015,2, 360-365

Au(I) π-bis(tert-butyldimethylsilyl)acetylene triphenylphosphine complex, an effective pre-catalyst for Au(I)-catalyzed reactions

D. Zhu, X. Cao and B. Yu, Org. Chem. Front., 2015, 2, 360 DOI: 10.1039/C5QO00023H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements