Issue 65, 2014
From the journal:

Chemical Communications

Nucleobase-functionalized ABC triblock copolymers: self-assembly of supramolecular architectures†

Keren Zhang,a   Gregory B. Fahs,a   Motohiro Aiba,a   Robert B. Moorea  and  Timothy E. Long*a  

* Corresponding authors

a Department of Chemistry, Macromolecules and Interfaces Institute, Virginia Tech, Blacksburg, VA 24061, USA
E-mail: telong@vt.edu

Abstract

RAFT polymerization afforded acrylic ABC triblock copolymers with self-complementary nucleobase-functionalized external blocks and a low-Tg soft central block. ABC triblock copolymers self-assembled into well-defined lamellar microphase-separated morphologies for potential applications as thermoplastic elastomers. Complementary hydrogen bonding within the hard phase facilitated self-assembly and enhanced mechanical performance.

Graphical abstract: Nucleobase-functionalized ABC triblock copolymers: self-assembly of supramolecular architectures

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Article information

DOI
https://doi.org/10.1039/C4CC03363A
Article type
Communication
Submitted
05 Mai 2014
Accepted
24 Jun 2014
First published
24 Jun 2014
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2014,50, 9145-9148

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Nucleobase-functionalized ABC triblock copolymers: self-assembly of supramolecular architectures

K. Zhang, G. B. Fahs, M. Aiba, R. B. Moore and T. E. Long, Chem. Commun., 2014, 50, 9145 DOI: 10.1039/C4CC03363A

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