Issue 45, 2013
From the journal:

CrystEngComm

Birefringent, emissive coordination polymers incorporating bis(benzimidazole)pyridine as an anisotropic building block†

John R. Thompson,ab   Ryan J. Roberts,a   Vance E. Williams*ab  and  Daniel B. Leznoff*a  

* Corresponding authors

a Department of Chemistry, Simon Fraser University, 8888 University Drive, Burnaby, British Columbia, Canada
E-mail: dleznoff@sfu.ca
Fax: +1 778 782 3765
Tel: +1 778 782 4887

b 4D LABS, Simon Fraser University, 8888 University Drive, Burnaby, British Columbia, Canada
E-mail: vancew@sfu.ca
Fax: +1 778 782 3765
Tel: +1 778 782 8059

Abstract

Coordination polymers Ln(BBP)2[Au(CN)2]3·2(CH3CN) (Ln = Eu, Gd) and Ln(BBP)(NO3)2[Au(CN)2]·(CH3CN) (Ln = Eu, Gd, Tb) have been synthesized. They incorporate bis(benzimidazole)pyridine (BBP), a highly anisotropic building block which, in conjunction with Ln centres and [Au(CN)2]− units generates the first highly birefringent, emissive coordination polymer materials.

Graphical abstract: Birefringent, emissive coordination polymers incorporating bis(benzimidazole)pyridine as an anisotropic building block

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Article information

DOI
https://doi.org/10.1039/C3CE41556B
Article type
Communication
Submitted
04 Aug 2013
Accepted
04 Sep 2013
First published
16 Okt 2013

CrystEngComm, 2013,15, 9387-9393

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Birefringent, emissive coordination polymers incorporating bis(benzimidazole)pyridine as an anisotropic building block

J. R. Thompson, R. J. Roberts, V. E. Williams and D. B. Leznoff, CrystEngComm, 2013, 15, 9387 DOI: 10.1039/C3CE41556B

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