Issue 3, 2010
From the journal:

Chemical Communications

Hydrogen evolution by cobalt tetraiminecatalysts adsorbed on electrode surfaces†

Louise A. Berbena  and  Jonas C. Peters*a  

* Corresponding authors

a Department of Chemistry, Massachusetts Institute of Technology, Cambridge, USA
E-mail: jcpeters@mit.edu
Fax: +1 617 324 1554
Tel: +1 617 253 1819

Abstract

Aryl-substituted tetraimine complexes related to Co(dmgBF2)2(MeCN)2 (dmg = dimethylglyoxime) were synthesized and are active for hydrogen evolution. Co(dmgBF2)2(MeCN)2 can be adsorbed to a glassy carbon electrode. The chemically modified electrode is active for hydrogen evolution in aqueous solution at pH < 4.5, with an overpotential of only 100 mV.

Graphical abstract: Hydrogen evolution by cobalt tetraimine catalysts adsorbed on electrode surfaces

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Article information

DOI
https://doi.org/10.1039/B921559J
Article type
Communication
Submitted
14 Okt 2009
Accepted
10 Nov 2009
First published
25 Nov 2009

Chem. Commun., 2010,46, 398-400

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Hydrogen evolution by cobalt tetraimine catalysts adsorbed on electrode surfaces

L. A. Berben and J. C. Peters, Chem. Commun., 2010, 46, 398 DOI: 10.1039/B921559J

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