Issue 12, 2023

Transition metal-free and regioselective alkenyl C–S cross-coupling reaction of alkenylsulfonium salts

Abstract

Herein, we report a novel and highly efficient strategy for the construction of alkenyl sulfoxides via transition metal-free C–S cross-coupling of sulfenate anions with alkenylsulfonium salts. This procedure features the capture of in situ generated sulfenate anions from β-sulfinyl esters under mild conditions, which provides an efficient strategy for the synthesis of diverse alkenyl sulfoxides in moderate to good yields.

Graphical abstract: Transition metal-free and regioselective alkenyl C–S cross-coupling reaction of alkenylsulfonium salts

Supplementary files

Article information

Article type
Research Article
Submitted
05 Apr 2023
Accepted
10 Mai 2023
First published
23 Mai 2023

Org. Chem. Front., 2023,10, 2907-2912

Transition metal-free and regioselective alkenyl C–S cross-coupling reaction of alkenylsulfonium salts

Q. Wang, S. Wu, Y. Wang, J. Sun, Y. Han, C. Yan and L. Wang, Org. Chem. Front., 2023, 10, 2907 DOI: 10.1039/D3QO00507K

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