Pb2.28Ba1.72B10O19 featuring a three-dimensional B–O anionic network with edge-sharing [BO4] obtained under ambient pressure

Siru Guo; Wenbin Zhang; Rong Yang; Min Zhang; Zhihua Yang; Shilie Pan

doi:10.1039/D1QI00653C

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Pb_2.28Ba_1.72B₁₀O₁₉ featuring a three-dimensional B–O anionic network with edge-sharing [BO₄] obtained under ambient pressure†

Siru Guo,^ab Wenbin Zhang,^ab Rong Yang,^ab Min Zhang,

*^ab Zhihua Yang

^ab and Shilie Pan

*^ab

Author affiliations

* Corresponding authors

^a CAS Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics & Chemistry, CAS; Xinjiang Key Laboratory of Electronic Information Materials and Devices, 40-1 South Beijing Road, Urumqi 830011, China
E-mail: zhangmin@ms.xjb.ac.cn, slpan@ms.xjb.ac.cn
Fax: +86-991-3838957
Tel: +86-991-3674558

^b Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

The first borate featuring a three-dimensional B–O anionic network with edge-sharing (ES) [BO₄] units, Pb_2.28Ba_1.72B₁₀O₁₉ (PbBaBO), has been synthesized under ambient pressure. The squeezing effect of the ²_∞[B₁₀O₁₉] bilayer structure on the intra-layer co-edge [BO₄] leads to an extremely long B–B distance and quite small internal O–B–O angles in the [B₂O₆] ring.

This article is part of the themed collection: 2021 Inorganic Chemistry Frontiers HOT articles

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Article information

DOI: https://doi.org/10.1039/D1QI00653C
Article type: Research Article
Submitted: 21 Mai 2021
Accepted: 14 Jun 2021
First published: 14 Jun 2021

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Inorg. Chem. Front., 2021,8, 3716-3722

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Pb_2.28Ba_1.72B₁₀O₁₉ featuring a three-dimensional B–O anionic network with edge-sharing [BO₄] obtained under ambient pressure

S. Guo, W. Zhang, R. Yang, M. Zhang, Z. Yang and S. Pan, Inorg. Chem. Front., 2021, 8, 3716 DOI: 10.1039/D1QI00653C

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