Issue 5, 2018

Carbazole-based compounds as photoinitiators for free radical and cationic polymerization upon near visible light illumination

Abstract

Six new carbazole based compounds (Ca1–Ca6) are synthesized and proposed as high performance photoinitiators with iodonium salt (iod) and/or an amine (EDB) for both the free radical polymerization (FRP) of acrylates and the cationic polymerization (CP) of epoxides upon near UV and visible light exposure using light emitting diodes (LEDs) @385 nm and @405 nm. Excellent polymerization initiating abilities are found and high final reactive function conversions are acquired. A full picture of the involved photochemical mechanisms is given.

Graphical abstract: Carbazole-based compounds as photoinitiators for free radical and cationic polymerization upon near visible light illumination

Supplementary files

Article information

Article type
Paper
Submitted
26 Okt 2017
Accepted
19 Mär 2018
First published
20 Mär 2018

Photochem. Photobiol. Sci., 2018,17, 578-585

Carbazole-based compounds as photoinitiators for free radical and cationic polymerization upon near visible light illumination

A. Al Mousawi, A. Arar, M. Ibrahim-Ouali, S. Duval, F. Dumur, P. Garra, J. Toufaily, T. Hamieh, B. Graff, D. Gigmes, J. Fouassier and J. Lalevée, Photochem. Photobiol. Sci., 2018, 17, 578 DOI: 10.1039/C7PP00400A

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