Issue 42, 2011
From the journal:

Chemical Communications

Simple routes to bulky silyl-substituted acetylideligands and examples of V(iii), Fe(ii), and Mn(ii) complexes†

Gereon M. Yee,a   Kristin Kowolik,a   Shuhei Manabe,a   James C. Fettingera  and  Louise A. Berben*a  

* Corresponding authors

a Department of Chemistry, University of California, Davis, CA, USA
E-mail: laberben@ucdavis.edu
Fax: (+1) 530 752 8995
Tel: (+1) 530 752 8475

Abstract

Synthesis of substituted phenylacetylide ligands 2,6-bis(trimethylsilyl)phenylacetylene (H1) and 2-(triphenylsilyl)phenylacteylene (H2) is reported. Ligand 1 supports tetrahedral complexes of V(III), Fe(II), and Mn(II) (3–5). Complexes 3–5 are high-spin and redox active.

Graphical abstract: Simple routes to bulky silyl-substituted acetylide ligands and examples of V(iii), Fe(ii), and Mn(ii) complexes

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Article information

DOI
https://doi.org/10.1039/C1CC14758G
Article type
Communication
Submitted
02 Aug 2011
Accepted
10 Sep 2011
First published
26 Sep 2011

Chem. Commun., 2011,47, 11680-11682

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Simple routes to bulky silyl-substituted acetylide ligands and examples of V(III), Fe(II), and Mn(II) complexes

G. M. Yee, K. Kowolik, S. Manabe, J. C. Fettinger and L. A. Berben, Chem. Commun., 2011, 47, 11680 DOI: 10.1039/C1CC14758G

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