The hybrid open-framework of tin(II) phosphonopropionate oxalate, Sn4(O3PCH2CH2CO2)2(C2O4)

Norbert Stock; Galen D. Stucky; Anthony K. Cheetham

doi:10.1039/B006511K

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The hybrid open-framework of tin(ii) phosphonopropionate oxalate, Sn₄(O₃PCH₂CH₂CO₂) ₂(C₂O₄)

Norbert Stock,^a Galen D. Stucky^a and Anthony K. Cheetham*^a

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* Corresponding authors

^a Materials Research Laboratory, University of California, Santa Barbara, CA 93106, USA.
E-mail: cheetham@mrl.ucsb.edu

^b Department of Chemistry, University of California, Santa Barbara, CA 93106, USA

Abstract

The hydrothermal synthesis and single crystal XRD characterization of a three-dimensional open-framework tin(II) phosphonopropionate oxalate, Sn₄(O₃PCH₂CH₂CO₂) ₂- (C₂O₄), is described; the structure contains two different bifunctional linkers as well as SnO₃ and SnO₄ polyhedra each with a stereochemically active lone pair of electrons, and exhibits several types of channels.

This article is part of the themed collection: In celebration of Tony Cheetham’s 70th birthday

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Supplementary files

Crystal structure data TXT (13K)

Article information

DOI: https://doi.org/10.1039/B006511K
Article type: Communication
Submitted: 08 Aug 2000
Accepted: 09 Okt 2000
First published: 06 Nov 2000

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Chem. Commun., 2000, 2277-2278

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The hybrid open-framework of tin(II) phosphonopropionate oxalate, Sn₄(O₃PCH₂CH₂CO₂) ₂(C₂O₄)

N. Stock, G. D. Stucky and A. K. Cheetham, Chem. Commun., 2000, 2277 DOI: 10.1039/B006511K

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