A Keggin-type polyoxometalate/COF thin separator for improving the performance of lithium–sulfur batteries

Wenhui Liu, Bo Sun, Yingkai Guan, Wei Xie, Chan Yao and Yanhong Xu

J. Mater. Chem. A, 2025, 13, 14064
DOI: 10.1039/D4TA09185J

A Co and Fe bimetallic MOF with enhanced electrocatalytic oxygen evolution performance: exploring the electronic environment modifications upon Fe incorporation

Varsha Singh, Devesh Kumar Singh, Mamta Yadav, Smita Singh, Vikram Rathour, Ananya Tiwari and Vellaichamy Ganesan

Energy Adv., 2024, 3, 636
DOI: 10.1039/D3YA00572K

Beyond conventional structures: emerging complex metal oxides for efficient oxygen and hydrogen electrocatalysis

Yinlong Zhu, Zheng Tang, Lingjie Yuan, Bowen Li, Zongping Shao and Wanlin Guo

Chem. Soc. Rev., 2025, 54, 1027
DOI: 10.1039/D3CS01020A

Stepwise synthesis of symmetric and asymmetric Anderson-polyoxometalates for light-driven hydrogen evolution

Patrick Endres, Garima Sachdeva, Andreas Winter, Dolores Díaz, Helmar Görls, Nicole Fritz, Christof Neumann, Andrey Turchanin, Carsten Streb and Ulrich S. Schubert

Inorg. Chem. Front., 2026, 13, 1442
DOI: 10.1039/D5QI02141C

Scalable, thermally stabilized MOF-graphene fibers with hierarchical porosity for high-performance energy storage devices

Narges Nobakht, Mohammad Hosseini, Seyyed Ahmad Etghani, Mohamad Ali Sanjari Shahrezaei, Ali Sajedi-Moghaddam and Seyed Hamed Aboutalebi

J. Mater. Chem. A, 2025, 13, 28532
DOI: 10.1039/D5TA02969D

Reaction of a Cp*Ir(iii) cation with mono- and di-lacunary Keggin-type heteropolytungstates and a dimer of a hexa-lacunary Dawson-type phosphopolytungstate

Sugiarto, Jun Shinogi, Sherif E. Ebied, Dachao Hong, Yoshihiro Kon and Masahiro Sadakane

Dalton Trans., 2026, 55, 775
DOI: 10.1039/D5DT02418H

Polyoxometalate-supported transition metal complexes for the oxidative cross-coupling of amines and alcohols

Ankita Pardiwala, Meghal A. Desai and Ritambhara Jangir

Dalton Trans., 2024, 53, 17207
DOI: 10.1039/D4DT02289K

An in situ dual modification strategy for enhancing the electrocatalytic oxygen evolution performance of ZIF-67

Rajesha Kumar Swain, Aranya Kar, Aditi Halder and Chullikkattil P. Pradeep

Dalton Trans., 2025, 54, 13294
DOI: 10.1039/D5DT01416F

Surfactant-assisted morphology modification of nanostructured MnMoO4 for high-performance asymmetric supercapacitors

Prasad Kumcham, T. V. M. Sreekanth, Kisoo Yoo and Jonghoon Kim

New J. Chem., 2024, 48, 7820
DOI: 10.1039/D4NJ00703D

Exploring the advances in 2D materials as a quest for energy storage electrode materials

Sebin Kariachan, Joshin Shibu, Prajitha Velayudhan, Sisanth Krishnageham Sidharthan, Pravitha Velayudhan, Sanu Mathew Simon, Hitoshi Kasai, Kohei Okubo, Sabu Thomas, Kouki Oka and Jibin Keloth Paduvilan

RSC Adv., 2026, 16, 10847
DOI: 10.1039/D5RA07292A

Development of polyoxometalate-loaded MOFs for heterogeneous catalysis and enhanced dye adsorption

Ketan Maru, Sarita Kalla and Ritambhara Jangir

Dalton Trans., 2025, 54, 298
DOI: 10.1039/D4DT02645D

17O NMR spectroscopy in polyoxometalate chemistry: advances, challenges, and applications in structure and catalysis

Thompson Izuagie and Daniel Lebbie

RSC Adv., 2026, 16, 6562
DOI: 10.1039/D5RA08401F

Redox-active modification of Dawson-type copper molybdate cluster for advanced supercapacitor applications

Ankita Pardiwala, Ravi Rajan Pandey, Anshu Andola, Rakesh K. Pandey and Ritambhara Jangir

Dalton Trans., 2026, 55, 492
DOI: 10.1039/D5DT02130H

Chiral chlorophyll-inspired clusters steering electron transfer for enhanced CO2 photoreduction

Yin-Hua Zhu, Jian-Bo Yang, Jiu Lin Zhou, Yong-Qi Ji, Hua Mei and Yan Xu

Green Chem., 2025, 27, 12778
DOI: 10.1039/D5GC03034J

Organofunctionalized borotungstate polyoxometalates as tunable photocatalysts for oxidative dimerization of amines

Nicole Tsang, Alexander J. Kibler, Stephen P. Argent, Hon Wai Lam, Kieran D. Jones and Graham N. Newton

Chem. Sci., 2024, 15, 14685
DOI: 10.1039/D4SC03534H

Interfacial engineering of a Ni3ZnC0.7/VN heterostructure with optimized dual metal sites for alkaline electrocatalytic hydrogen evolution

Liangliang Feng, Kaikai Zhao, Lina Dai, Danyang He, Hongyan Yin, Yonghui Zhang, Jingyi Chen, Liyun Cao and Jianfeng Huang

Mater. Chem. Front., 2025, 9, 1596
DOI: 10.1039/D5QM00113G

Recent advances and future research directions in polyoxometalate-based water electrolysis for hydrogen production

Houen Zhu, Shumao Yuan, Yafu Wang, Zhihua Zhang, Zhenlin Zhao, Ke Yang, Zhencheng Feng, Jianqi Lu, Xiangyu Liu, Fanchentao Sun and Jiangwei Zhang

Polyoxometalates, 2026, 5, 9140112
DOI: 10.26599/POM.2026.9140112

Review—Advances in Rechargeable Lithium-Ion Batteries Utilizing Polyoxometalate-Functionalized Nanocarbon Materials

Samaneh Shahsavarifar, Morteza Rezapour, Mehdi Mehrpooya, Hermann Ehrlich, Teofil Jesionowski, Mohammad Reza Ganjali, Rafael Luque and Mehdi Rahimi-Nasrabadi

J. Electrochem. Soc., 2024, 171, 080536
DOI: 10.1149/1945-7111/ad6b46

Advancements in Atomically Precise Nanocluster Protected by Thiacalix[4]arene

Rakesh Kumar Gupta, Zhi Wang, Brij Mohan, Chen‐Ho Tung and Di Sun

Advanced Materials, 2024, 36
DOI: 10.1002/adma.202410054

Sustainable Electroreduction of Oxygen: Polyoxometalate-Carbon Composites as a Noble Metal-Free Catalyst

Subash Mohandoss, Sagar Ingavale, Anita Swami and Natarajan Balasubramaniyan

Energy Fuels, 2025, 39, 12217
DOI: 10.1021/acs.energyfuels.5c01644

Polyoxometalate-based materials for electrochemical energy storage and catalytic hydrogen production

Qian Wang, Guangning Wang, Hongyan Ren, Zihao Li, Chunjing Zhang, Tingting Chen and Haijun Pang

Coordination Chemistry Reviews, 2025, 545, 217044
DOI: 10.1016/j.ccr.2025.217044

MnMoO4 Sub‐Nano Sheets as Anode Materials for High‐Performance Lithium‐Ion Batteries

Yanchun Liu, Jingze Zhang, Xianggang Zhou, Guobang Li, Mengkai Wang, Ruiqi Yao, Yingqi Li and Qingda Liu

Small, 2026, 22
DOI: 10.1002/smll.202514787

Implications of Charge and Heteroatom Dopants on the Thermodynamics and Kinetics of Redox Reactions in Keggin-Type Polyoxometalates

Mamta Dagar, Anyesh De, Zhou Lu, Ellen M. Matson and Agnes E. Thorarinsdottir

ACS Mater. Au, 2025, 5, 200
DOI: 10.1021/acsmaterialsau.4c00136

Bidentate/bis-bidentate ligands−contained polymolybdate−based hybrid copper compounds for capacitive performance and catalytic detoxification of sulfur mustard simulant

Ji-Sheng Wang, Yi-Ming Li, Yu Bai and Xiang Wang

Polyhedron, 2026, 286, 117941
DOI: 10.1016/j.poly.2025.117941

Organoarsonate- and Dimethylarsinate-Functionalized Hexamolybdates(V): A Multifaceted Study on Synthesis, Structural Dynamics, and Antibacterial Properties

Vinaya Siby, Arun Pal, Anupam Sarkar, Bassem S. Bassil, Anneke Immoor, James Ziemah, Jana Hölscher, Levente Kiss, Cristian Silvestru, Matthias S. Ullrich, Nikolai Kuhnert and Ulrich Kortz

Inorg. Chem., 2025, 64, 17890
DOI: 10.1021/acs.inorgchem.5c02852

Morphology Effects on Free Energies of Proton-Coupled Electron Transfer in Polyoxotungstates

Andreas Towarnicky, Zhou Lu, Ellen M. Matson and Giannis Mpourmpakis

Inorg. Chem., 2025, 64, 23834
DOI: 10.1021/acs.inorgchem.5c02910

Purely Inorganic {P4Mo6O31}‐Based Polyoxometalates Materials Enabling Electrochemical Energy Storage

Chen Wang, Feng‐Zhi Wang, Song Liang and Hong‐Ying Zang

Electron, 2025, 3
DOI: 10.1002/elt2.70019

Electrode–Polyoxometalate Interactions: Adsorption‐Driven Control of Redox Properties in Polyoxometalates

Avra Tzaguy, Dima Azaiza‐Dabbah and Ronny Neumann

ChemElectroChem, 2025, 12
DOI: 10.1002/celc.202500329

Two-dimensional MBenes for next-generation energy storage and electrocatalysis

Chhavi Jaswal, Manjot Kaur and Akshay Kumar

Applied Energy, 2026, 414, 127799
DOI: 10.1016/j.apenergy.2026.127799

Temperature-induced phase transformation/transition in K6Mo7O24·4H2O

Walajhone O. Pereira, João V.B. Moura, Rossano Lang, Clenilton C. dos Santos, Alan S. de Menezes and Adenilson O. dos Santos

Materials Chemistry and Physics, 2025, 345, 131315
DOI: 10.1016/j.matchemphys.2025.131315

MOF derived ZnO nanostructures modified with CoW12-polyoxometalates for enhanced sunlight driven degradation of methylene blue, ofloxacin and their mixtures

Nitin A. Tupsamindar, Arun S. Chopade, Sagar A. Chaudhari, Abhijit N. Kadam, Sandip R. Sabale, Vaishali Patil, Mohaseen S. Tamboli, Raisuddin Ali, Nguyen Tam Nguyen Truong, Vashishtha M. Gurame, Dattakumar S. Mhamane, Vijaykumar P. Ubale, Rajkumar Patel and Mukund G. Mali

Journal of Water Process Engineering, 2025, 79, 108959
DOI: 10.1016/j.jwpe.2025.108959

Polyoxometalates based transition metal sulfide composites for hydrodesulfurization and hydrogen evolution reaction

Ghulam Murtaza, Tayyaba Najam, Naseem Ahmad Khan, Muhammad Sher, Muhammad Kashif Aslam, Ibrahim A. Shaaban, Muhammad Altaf Nazir, Manzar Sohail and Syed Shoaib Ahmad Shah

International Journal of Hydrogen Energy, 2025, 98, 527
DOI: 10.1016/j.ijhydene.2024.12.048

Kinetic insights into the integration of polyoxometalate clusters on reduced graphene oxide for enhanced electrochemical performance in energy storage applications

Serena Nogueira Cesario, Bianca Tainá Ferreira, Matheus Martins, Pedro Gómez-Romero and Fritz Huguenin

J Solid State Electrochem, 2025, 29, 1841
DOI: 10.1007/s10008-024-06131-x

Amorphous electrocatalysts for oxygen and hydrogen evolution reactions: Advances in hydrogen production

Selvam Mathi, Hanan Akhdar, Ranjan S. Shetti, Tarfah Alinad, Abdullah N. Alodhayb, Kunal Mondal and Nagaraj P. Shetti

Materials Today Sustainability, 2025, 32, 101223
DOI: 10.1016/j.mtsust.2025.101223

Overview of Wells-Dawson Polyoxometalates: from structure and functionalization to application

Daria Nowicka, Nahir Vadra, Ewelina Wieczorek-Szweda, Violetta Patroniak and Adam Gorczyński

Coordination Chemistry Reviews, 2024, 519, 216091
DOI: 10.1016/j.ccr.2024.216091

Tuning the Bifunctional La2Ni1.8Fe0.2O6/rGO Nanocomposites for Supercapacitor and Water Splitting Applications

I. Ajin and A. Chandra Bose

Energy Fuels, 2026, 40, 1786
DOI: 10.1021/acs.energyfuels.5c05971

CdWO4 Sub‐1 nm Nanowires for Visible‐Light CO2 Photoreduction

Yan‐Chun Liu, Chang‐Yan Zhu, Xia Zhao, Hua‐Qiao Tan, Si‐Hang Cheng, Dan Yang, Xun Wang and Yang‐Guang Li

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202418349

Synergistic MXene (Ti3C2Tx)/ Polyoxomolybdate (PMo12) Hybrid Anode for Robust and High-Performance Lithium-Ion Batteries

Neha D. Panchal and Helen Annal Therese

ACS Appl. Nano Mater., 2025, 8, 24402
DOI: 10.1021/acsanm.5c04412

Polyoxometalates metal–organic frameworks-derived transition metal sulfides with rich interfaces for efficient alkaline oxygen evolution reaction

Zonish Zeb, Yichao Huang, Lulu Chen, Ruili Gao, Xiaohui Gao, Mengdi Sun, Hanqing Cai, Jiangchuan Chen, Faheem Abbas, Meihong Liao, Lubin Ni and Yongge Wei

Journal of Colloid and Interface Science, 2025, 686, 289
DOI: 10.1016/j.jcis.2025.01.221

Enhanced Electrocatalytic Hydrogen Peroxide Production via a CuWO4/WO3 Heterojunction with High Selectivity and Stability

Yu Liu, Hongxiao Liu, Junning Qian, Jian Luan, Yongbiao Mu, Cailin Xiao, Qing Zhang, Su Shiung Lam, Wenjia Li and Lin Zeng

ACS Appl. Mater. Interfaces, 2025, 17, 5026
DOI: 10.1021/acsami.4c19881

Polyoxometalate electrocatalysts supported on nickel foam for enhanced oxygen evolution in alkaline media

Zonish Zeb, Nisar Khan, Zheyu Wei, Yuanyuan Li, Ruili Gao, Yanfei Wang, Yichao Huang and Lubin Ni

Polyoxometalates, 2026, 5, 9140123
DOI: 10.26599/POM.2026.9140123

Investigation on the Keggin Anchored on Hydroxide-Functionalized Single-Walled Carbon Nanotubes as Superior Cathode for Aqueous Zinc-Ion Batteries

Langson Chilufya, Vahide Sertbaş, Ahmet Aytekin, Engin Karabudak and Mehtap Emirdag-Eanes

ACS Omega, 2025, 10, 36536
DOI: 10.1021/acsomega.5c05213

Sprayed Microdroplets Architect a Polyoxometalate Framework

Abhijit Nandy, Gajiram Murmu, Anitesh Rana, Sumit Saha and Shibdas Banerjee

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202424745

Engineered PW12-polyoxometalate docked Fe sites on CoFe hydroxide anode for durable seawater electrolysis

Xun He, Yongchao Yao, Min Zhang, Yilei Zhou, Limei Zhang, Yuchun Ren, Kai Dong, Hong Tang, Jue Nan, Xingli Zhou, Han Luo, Binwu Ying, Qi Yu, Fengming Luo, Bo Tang and Xuping Sun

Nat Commun, 2025, 16
DOI: 10.1038/s41467-025-60620-9

Uncovering multielectron transfer in phosphomolybdate cluster electrolytes for redox flow battery application

Yuliya Ivanova, Carlos Almeida, Dzmitry Ivanou and Adélio Mendes

Chemical Engineering Journal, 2025, 522, 166948
DOI: 10.1016/j.cej.2025.166948

Synthesis and characterization of new tri- titanum substituted Keggin-type polyoxometalate (PW9Ti3O40) for enhanced photocatalytic water oxidation performance

Seyed Mohammad Ali Abdollah pour Aghdam Sharabiani and Mohammad Ali Rezvani

Inorganica Chimica Acta, 2026, 589, 122949
DOI: 10.1016/j.ica.2025.122949

POM-Mediated Synthesis of Ag/PW12/g-C3N4 Nanocomposite Exhibiting Enhanced Photocatalytic Performance Under Visible Light

Huimin Liu, Qiuci Yu, Wei Chen, Shuge Tang, Xiaojia Feng, Chi Ma and Linlin Tian

Catalysts, 2024, 14, 912
DOI: 10.3390/catal14120912

Recent advances in the heavy metals removal using ammonium molybdophosphate composites: A review

Youssef Miyah, Noureddine El Messaoudi, Mohammed Benjelloun, Omar Boualam, Brahim Aasli, Besma Graba, Jordana Georgin, María F. Alexandre-Franco and Salah Knani

Advances in Colloid and Interface Science, 2025, 343, 103559
DOI: 10.1016/j.cis.2025.103559

Sprayed Microdroplets Architect a Polyoxometalate Framework

Abhijit Nandy, Gajiram Murmu, Anitesh Rana, Sumit Saha and Shibdas Banerjee

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202424745

Polyoxometalates’ Progress for the Treatment of Alzheimer’s Disease

Manuel Aureliano, João Mateus and David Manjua Rijo

BioChem, 2025, 5, 41
DOI: 10.3390/biochem5040041

Hybrid MXenes for supercapacitors: Advances, mechanisms, and outlook

Sonika and Narinder Singh

Materials Today Physics, 2025, 59, 101947
DOI: 10.1016/j.mtphys.2025.101947

Bioinspired polyoxometalates as light-driven water oxidation catalysts

Eduardo Sánchez-Lara, Roberto Favela and Ivan Castillo

Front. Chem. Biol., 2024, 3
DOI: 10.3389/fchbi.2024.1373647

CdWO4 Sub‐1 nm Nanowires for Visible‐Light CO2 Photoreduction

Yan‐Chun Liu, Chang‐Yan Zhu, Xia Zhao, Hua‐Qiao Tan, Si‐Hang Cheng, Dan Yang, Xun Wang and Yang‐Guang Li

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202418349

Optimizing Polyoxometalate Electrodes for Energy Storage via Cation Design and Thermal Activation

Lucía Vizcaíno‐Anaya, Óscar Giner‐Rajala, Carlos Herreros‐Lucas, Héctor Rodríguez and María del Carmen Giménez‐López

Chemistry Methods, 2025, 5
DOI: 10.1002/cmtd.202500046

Transition metal polyoxometalates with reduced graphene oxide for high-performance air-electrode of metal-air batteries

Filipe M.B. Gusmão, Teodora Đurić, Jadranka Milikić, Kristina Radinović, Diogo M.F. Santos, Dalibor Stanković and Biljana Šljukić

International Journal of Hydrogen Energy, 2024, 71, 763
DOI: 10.1016/j.ijhydene.2024.05.229

Heterogeneous Polyoxometalate‐Based Catalysts for Functionalized Quinones Synthesis: Systematic Advances, Prospects, and Challenges

Shenzhen Chang, Yanhong Chen, Jinhao Zhang, Qinhe Pan and Yingjie Hua

ChemPlusChem, 2025, 90
DOI: 10.1002/cplu.202500261

Nitrite Electroreduction Enhanced by Hybrid Compounds of Keggin Polyoxometalates and 1‐Butyl‐3‐Vinylimidazolium

Yulin Zhou, Jing Sun, Sébastien Gallet, Jesus Raya, Corinne Boudon, Antoine Bonnefont, Laurent Ruhlmann and Vasilica Badets

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202400226

Unique Structural Features of Polyoxometalates for Efficient Alkaline Hydrogen‐Evolution Reaction

Mingtao Chu, Teng Zhang, Ping Song, Ce Han and Weilin Xu

ChemSusChem, 2026, 19
DOI: 10.1002/cssc.202502761

Synthesis, Characterization of Transition Metal (Mn, V) based Silverton Type Anion and its Antioxidant and Antimicrobial Studies

Alphonse Lazar, Rajesh Kumar, Vickram Mani, Bharath Samannan and Jeyabalan Thavasikani

ajc, 2025, 37, 2155
DOI: 10.14233/ajchem.2025.32841

Unleashing asymmetric polyoxometalate redox activators on 2D interfaces for high-performance hybrid energy storage

Arya Das, Mamata Mohapatra and Suddhasatwa Basu

Carbon, 2024, 223, 119007
DOI: 10.1016/j.carbon.2024.119007

Recent Advances in Polyoxometalate‐Based Materials as Anodes for Lithium‐Ion Batteries

Ming‐Yue Yu, Xue‐Zhen Li, Li Zhang, Yu‐Ling Jia, Fang Zou, Zhen‐Long Liu, Xin‐Wen Zhang, Qian Zhang, Jin‐Hua Liu, Wen Li and Yan‐Qing Wang

ChemistrySelect, 2025, 10
DOI: 10.1002/slct.202503244

Unlocking the opportunities of POM@MOF composites as next catalyst for energy and environmental remediation applications

Abdurrashid Haruna, Zakariyya Uba Zango, Muhammad Abubakar Lawal, Gazali Tanimu, Zaharadden N. Garba, Thompson Izuagie, Suleiman Gani Musa, Zulkfli Merican Aljunid Merican, Haruna Adamu and Ying Zheng

Materials Research Bulletin, 2026, 198, 113993
DOI: 10.1016/j.materresbull.2026.113993

Mn-modified phosphomolybdates by hydrothermal route for pseudocapacitor application

Nusrat Tazeen Tonu, Mohammad Abu Yousuf and Hiroshi Yabu

PLoS One, 2026, 21, e0346559
DOI: 10.1371/journal.pone.0346559

Beneficial role of silicotungstic acid presence on the WO3-modified boron-doped diamond substrate on the electrocatalytic activity for methanol anodic oxidation of supported platinum

Nicolae Spătaru, Loredana Preda, Elena Matei, Veronica Satulu, Marius Alexandru Mihai, Mihai Marian Radu, Cristina Donath, Olivia Georgeta Moga and Tanţa Spătaru

International Journal of Hydrogen Energy, 2025, 120, 403
DOI: 10.1016/j.ijhydene.2025.03.327