Catalytic H/D exchange of (hetero)arenes with early–late polyhydride heterobimetallic complexes: impact of transition metal pairs

Abdelhak Lachguar, Till Neumann, Andrey V. Pichugov, Erwann Jeanneau, Laurent Veyre, Chloé Thieuleux and Clément Camp

Dalton Trans., 2025, 54, 3804
DOI: 10.1039/D4DT03171G

Synergistic C–H bond activation across molybdenum–iridium multiply bonded complexes: a cascade of transformations

Zachary Dubrawski, Iker Del Rosal, Erwann Jeanneau, Laurent Maron, Chloé Thieuleux and Clément Camp

Chem. Sci., 2025, 16, 14564
DOI: 10.1039/D5SC03465E

Reduction of CS2 to an ethanetetrathiolate by a hydride-bridged uranium–iridium heterobimetallic complex

Christopher Z. Ye, Iker Del Rosal, Erik T. Ouellette, Stephan Hohloch, Laurent Maron, Clément Camp and John Arnold

Chem. Commun., 2024, 60, 12377
DOI: 10.1039/D4CC02482F

Revisiting the structure and properties of mid-valent monopentamethylcyclopentadienylchromium complexes

Adrián Calvo-Molina, Jesús Jover, Adrián Pérez-Redondo and Carlos Yélamos

Dalton Trans., 2025, 54, 8190
DOI: 10.1039/D5DT00620A

CO2 cleavage by tantalum/M (M = iridium, osmium) heterobimetallic complexes

Abdelhak Lachguar, Christopher Z. Ye, Sheridon N. Kelly, Erwann Jeanneau, Iker Del Rosal, Laurent Maron, Laurent Veyre, Chloé Thieuleux, John Arnold and Clément Camp

Chem. Commun., 2024, 60, 7878
DOI: 10.1039/D4CC02207F

PuCl3{CoCp[OP(OEt)2]3}: transuranic elements entering the field of heterometallic molecular chemistry

Thomas E. Shaw, Zachary R. Jones, Sara L. Adelman, Nickolas H. Anderson, Eric G. Bowes, Eric D. Bauer, David Dan, Jan Klouda, Karah E. Knope, Stosh A. Kozimor, Molly M. MacInnes, Veronika Mocko, Francisca R. Rocha, Harrison D. Root, Benjamin W. Stein, Joe D. Thompson and Jennifer N. Wacker

Chem. Sci., 2024, 15, 12754
DOI: 10.1039/D4SC01767F

Cooperative activation of carbon–hydrogen bonds by heterobimetallic systems

Abdelhak Lachguar, Andrey V. Pichugov, Till Neumann, Zachary Dubrawski and Clément Camp

Dalton Trans., 2024, 53, 1393
DOI: 10.1039/D3DT03571A

Visible-light driven H2 reductive elimination unlocks reactivity in polyhydrido niobium iridium clusters

Zachary Dubrawski, Samy Aïssiou, Erwann Jeanneau, Chloé Thieuleux and Clément Camp

Dalton Trans., 2026, 55, 620
DOI: 10.1039/D5DT02432C

f-Block hydride complexes – synthesis, structure and reactivity

Richard Drummond Turnbull and Nicola L. Bell

Dalton Trans., 2024, 53, 12814
DOI: 10.1039/D4DT00776J

Photolysis-driven bond activation by thorium and uranium tetraosmate polyhydride complexes

Christopher Z. Ye, Iker Del Rosal, Sheridon N. Kelly, I. Joseph Brackbill, Laurent Maron, Clément Camp and John Arnold

Chem. Sci., 2024, 15, 9784
DOI: 10.1039/D4SC02380C

Planar Tetranuclear Uranium Hydride Cluster Supported by ansa‐Bis(cyclopentadienyl) Ligands

Kai Li, Iker del Rosal, Yue Zhao, Laurent Maron and Congqing Zhu

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202405494

Synthesis, Structure, and Bonding of Actinide–Rhenium Polyhydrides

Christopher Z. Ye, Iker Del Rosal, Sheridon N. Kelly, Erik T. Ouellette, Laurent Maron, Clément Camp and John Arnold

Inorg. Chem., 2024, 63, 21167
DOI: 10.1021/acs.inorgchem.4c03449

Heterometallic coordination clusters and frameworks incorporating 3d–4f, 4d–4f, 5d–4f, and f-block metal combinations: Structures, properties, and applications

Divya Bajpai Tripathy, Subhalaxmi Pradhan and Pooja Agarwal

Inorganica Chimica Acta, 2026, 596, 123121
DOI: 10.1016/j.ica.2026.123121

Planar Tetranuclear Uranium Hydride Cluster Supported by ansa‐Bis(cyclopentadienyl) Ligands

Kai Li, Iker del Rosal, Yue Zhao, Laurent Maron and Congqing Zhu

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202405494

Thorium(iv)–antimony complexes exhibiting single, double, and triple polar covalent metal–metal bonds

Jingzhen Du, Kevin Dollberg, John A. Seed, Ashley J. Wooles, Carsten von Hänisch and Stephen T. Liddle

Nat. Chem., 2024, 16, 780
DOI: 10.1038/s41557-024-01448-6

Alkane Elimination Preparation of Heterobimetallic MoAl Tetranuclear and Binuclear Complexes Promoting THF Ring Opening

Léon Escomel, Erwann Jeanneau, Chloé Thieuleux and Clément Camp

Inorganics, 2024, 12, 72
DOI: 10.3390/inorganics12030072

π-Bonding of Group 11 Metals to a Tantalum Alkylidyne Alkyl Complex Promotes Unusual Tautomerism to Bis-alkylidene and CO2 to Ketenyl Transformation

Abdelhak Lachguar, Iker Del Rosal, Laurent Maron, Erwann Jeanneau, Laurent Veyre, Chloé Thieuleux and Clément Camp

J. Am. Chem. Soc., 2024, 146, 18306
DOI: 10.1021/jacs.4c02172

Flash Communication: Well-Defined Paramagnetic Polyhydrido-Bridged Iron–Iridium Clusters

Zachary Dubrawski, Billie Shearman, Naïme Soulé, Erwann Jeanneau, Chloé Thieuleux and Clément Camp

Organometallics, 2025, 44, 2151
DOI: 10.1021/acs.organomet.5c00301