Issue 7, 2022

Recent advances in low-power-threshold nonlinear photochromic materials

Abstract

Incoherent nonlinear photophysical and photochemical processes based on stepwise two-photon absorption (2PA) processes have been recently used in materials science owing to their unique photoresponses beyond one-photon processes and lower power thresholds to induce the processes than those of coherent nonlinear optical processes. Among them, nonlinear photochromic materials have received considerable attention because they exhibit unconventional photoresponses compared with other incoherent nonlinear processes such as low-power-threshold nonlinear photoresponses with unimolecular systems, gated photochemical reactions and oxygen-insensitive nonlinear photoresponses. Nonlinear photochromic materials are important not only for colorimetric materials, but also for emergent materials that can enrich the next-generation society such as dynamic holographic materials, which are promising for three-dimensional displays. In this tutorial review, we introduce low-power-threshold nonlinear photochromic materials using stepwise 2PA processes. First, we explain the fundamental concepts of photochemistry as well as photochromic reactions. We attempt to provide an intuitive understanding of incoherent nonlinear optical processes using these fundamental concepts. Then, we introduce several recent examples and potential applications of nonlinear photochromic materials. This tutorial review is important for understanding the scientific progress related to these fields and provides a simple unified picture of the incoherent nonlinear optical properties of different types of photofunctional materials.

Graphical abstract: Recent advances in low-power-threshold nonlinear photochromic materials

Article information

Article type
Tutorial Review
Submitted
10 dec 2021
First published
08 mar 2022

Chem. Soc. Rev., 2022,51, 2397-2415

Recent advances in low-power-threshold nonlinear photochromic materials

Y. Kobayashi and J. Abe, Chem. Soc. Rev., 2022, 51, 2397 DOI: 10.1039/D1CS01144H

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