Issue 5, 2015

Pt@ZIF-8 composite for the regioselective hydrogenation of terminal unsaturations in 1,3-dienes and alkynes

Abstract

Pt@ZIF-8 composites with crystallite sizes of ca. 150 nm were synthesized. The composite was used as a catalyst for the regioselective hydrogenation of trans-1,3-hexadiene to 3-hexene. 1-Hexyne was hydrogenated to 1-hexene and hexane while 3-hexyne did not react. In all cases, the Pt@ZIF-8 composite had higher selectivity than Pt/C.

Graphical abstract: Pt@ZIF-8 composite for the regioselective hydrogenation of terminal unsaturations in 1,3-dienes and alkynes

Supplementary files

Article information

Article type
Research Article
Submitted
20 jan 2015
Accepted
18 feb 2015
First published
06 mar 2015

Inorg. Chem. Front., 2015,2, 448-452

Author version available

Pt@ZIF-8 composite for the regioselective hydrogenation of terminal unsaturations in 1,3-dienes and alkynes

C. J. Stephenson, J. T. Hupp and O. K. Farha, Inorg. Chem. Front., 2015, 2, 448 DOI: 10.1039/C5QI00010F

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