Issue 1, 2015

A metal–organic framework as a highly efficient and reusable catalyst for the solvent-free 1,3-dipolar cycloaddition of organic azides to alkynes

Abstract

A new highly efficient and reusable Cu-MOF has been developed for the regioselective synthesis of 1,2,3-triazoles via the 1,3-dipolar cycloaddition of organic azides to terminal alkynes under solvent-free conditions. This protocol has the advantages of excellent product yields and a low catalyst loading. Moreover, the catalyst may be recovered and reused efficiently up to 5 cycles without major loss of reactivity.

Graphical abstract: A metal–organic framework as a highly efficient and reusable catalyst for the solvent-free 1,3-dipolar cycloaddition of organic azides to alkynes

Supplementary files

Article information

Article type
Research Article
Submitted
24 sep 2014
Accepted
06 nov 2014
First published
14 nov 2014

Inorg. Chem. Front., 2015,2, 42-46

A metal–organic framework as a highly efficient and reusable catalyst for the solvent-free 1,3-dipolar cycloaddition of organic azides to alkynes

P. Li, S. Regati, H. Huang, H. D. Arman, J. C.-G. Zhao and B. Chen, Inorg. Chem. Front., 2015, 2, 42 DOI: 10.1039/C4QI00148F

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