Issue 85, 2012

Understanding excess uptake maxima for hydrogen adsorption isotherms in frameworks with rht topology

Abstract

For a series of metal–organic frameworks with rht topology, we study computationally the effect of the linker length on the surface area, pore size, and pore volume, relating them with the hydrogen adsorption properties. The results provide new insights about the excess capacities and the pressures where the uptake maxima in the excess isotherms occur. We found that, of the materials studied, NU-109/L7 has the optimal pore volume for excess gravimetric hydrogen uptake.

Graphical abstract: Understanding excess uptake maxima for hydrogen adsorption isotherms in frameworks with rht topology

Supplementary files

Article information

Article type
Communication
Submitted
06 aug 2012
Accepted
06 sep 2012
First published
10 sep 2012

Chem. Commun., 2012,48, 10496-10498

Understanding excess uptake maxima for hydrogen adsorption isotherms in frameworks with rht topology

D. Fairen-Jimenez, Y. J. Colón, O. K. Farha, Y. Bae, J. T. Hupp and R. Q. Snurr, Chem. Commun., 2012, 48, 10496 DOI: 10.1039/C2CC35711A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements