Issue 4, 2003

Liquid clathrate formation in ionic liquid–aromatic mixtures

Abstract

1-Alkyl-3-methylimidazolium containing ionic liquids with hexafluorophosphate, bis(trifyl)imide, tetrafluoroborate, and chloride anions form liquid clathrates when mixed with aromatic hydrocarbons; in the system 1,3-dimethylimidazolium hexafluorophosphate–benzene, the aromatic solute could be trapped in the solid state forming a crystalline 2∶1 inclusion compound.

Graphical abstract: Liquid clathrate formation in ionic liquid–aromatic mixtures

Supplementary files

Article information

Article type
Communication
Submitted
21 dec 2002
Accepted
02 jan 2003
First published
21 jan 2003

Chem. Commun., 2003, 476-477

Liquid clathrate formation in ionic liquid–aromatic mixtures

J. D. Holbrey, W. M. Reichert, M. Nieuwenhuyzen, O. Sheppard, C. Hardacre and R. D. Rogers, Chem. Commun., 2003, 476 DOI: 10.1039/B212726A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements