Issue 51, 2024

CsAlB3O6Cl: the rational construction of a KBBF-type structure with aligned 2[AlB3O6Cl] layers via introducing unprecedented [AlO3Cl] tetrahedra

Abstract

The first chloroaluminoborate, CsAlB3O6Cl, with innovative AlO3Cl tetrahedra and a perfect planar arrangement of [B3O6] groups, was structurally designed and synthesized via chlorination of [AlO4] tetrahedra. Simultaneously, the smooth introduction of the [AlO3Cl] group into borates initiates the development of a chloroaluminoborate and greatly enriches the structural chemistry of aluminoborates.

Graphical abstract: CsAlB3O6Cl: the rational construction of a KBBF-type structure with aligned 2∞[AlB3O6Cl] layers via introducing unprecedented [AlO3Cl] tetrahedra

Supplementary files

Article information

Article type
Communication
Submitted
18 apr 2024
Accepted
20 maj 2024
First published
23 maj 2024

Chem. Commun., 2024,60, 6516-6519

CsAlB3O6Cl: the rational construction of a KBBF-type structure with aligned 2[AlB3O6Cl] layers via introducing unprecedented [AlO3Cl] tetrahedra

H. Liu, J. Jiao, A. Tudi, Q. Liu, Z. Yang, S. Pan and M. Zhang, Chem. Commun., 2024, 60, 6516 DOI: 10.1039/D4CC01827C

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