Issue 30, 2021

A {Na2Fe10} isobutyrate cluster, interlinked into 1D chains

Abstract

Charge-neutral [Na2Fe10O6(OH)4(isobutyrate)14(MeO)2(MeCN)2] coordination clusters, comprising a hollow ‘Chinese lantern’-like shell of six condensed planar triangular {FeIII33-O)} motifs, form upon ultrasonication of trinuclear Fe(III) isobutyrate units in acetonitrile in the presence of sodium azide and 4,4′-bipyridine (bpy), resulting in {[Na2Fe10O6(OH)4(isobutyrate)14(bpy)(MeO)2(MeCN)2]·MeOH}n in which the dodecanuclear cluster units are bpy-bridged into 1D chains.

Graphical abstract: A {Na2Fe10} isobutyrate cluster, interlinked into 1D chains

Supplementary files

Article information

Article type
Communication
Submitted
10 jun 2021
Accepted
19 jul 2021
First published
20 jul 2021

CrystEngComm, 2021,23, 5153-5156

A {Na2Fe10} isobutyrate cluster, interlinked into 1D chains

D. Podgornii, J. van Leusen, V. Ch. Kravtsov, P. Kögerler and S. G. Baca, CrystEngComm, 2021, 23, 5153 DOI: 10.1039/D1CE00777G

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