Issue 11, 2020
From the journal:

Chemical Science

A germaaluminocene†

Lena Albers, ORCID logo *a   Patrik Tholen,a   Marc Schmidtmann ORCID logo a  and  Thomas Müller ORCID logo *a  

* Corresponding authors

a Institute of Chemistry, Carl von Ossietzky University Oldenburg, Carl von Ossietzky-Straße 9-11, D-26129 Oldenburg, Federal Republic of Germany
E-mail: lena.albers@uni-oldenburg.de, thomas.mueller@uni-oldenburg.de

Abstract

The reactions of dipotassium germacyclopentadienediide with two Group 13 dichlorides, Cp*BCl2 and Cp*AlCl2, yield two structurally different products. In the case of boron a borole complex of germanium(II) is obtained. The aluminium halide gives an unprecedented neutral germaaluminocene. Both compounds were fully characterised by multinuclear NMR spectroscopy supported by DFT computations. The molecular structure of the germaaluminocene was determined by XRD.

Graphical abstract: A germaaluminocene

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Article information

DOI
https://doi.org/10.1039/D0SC00401D
Article type
Edge Article
Submitted
21 jan 2020
Accepted
07 feb 2020
First published
10 feb 2020
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2020,11, 2982-2986

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A germaaluminocene

L. Albers, P. Tholen, M. Schmidtmann and T. Müller, Chem. Sci., 2020, 11, 2982 DOI: 10.1039/D0SC00401D

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