Issue 10, 2020

Effects of solvents, additives, and π-allyl ligand structures on the polymerization behavior of diazoacetates initiated by π-allylPd complexes

Abstract

In the polymerization of diazoacetates initiated by π-allylPd-based initiating systems, the effects of solvents, additives, and π-allyl ligand structures on the polymerization behavior were investigated. As a result, the polymerization in the presence of pyridine or its derivatives as an additive was found to afford a polymer with relatively narrow molecular weight distribution compared to that with π-allylPdCl alone. Furthermore, we have demonstrated that Pd complexes with π-allyl ligands with a variety of substituents are capable of polymerizing diazoacetates in a similar manner to the parent unsubstituted π-allylPdCl, and the tacticity of the resulting polymers is affected by the structure of the π-allyl ligands.

Graphical abstract: Effects of solvents, additives, and π-allyl ligand structures on the polymerization behavior of diazoacetates initiated by π-allylPd complexes

Supplementary files

Article information

Article type
Paper
Submitted
02 nov 2019
Accepted
21 jan 2020
First published
22 jan 2020

Polym. Chem., 2020,11, 1774-1784

Effects of solvents, additives, and π-allyl ligand structures on the polymerization behavior of diazoacetates initiated by π-allylPd complexes

H. Shimomoto, M. Nakajima, A. Watanabe, H. Murakami, T. Itoh and E. Ihara, Polym. Chem., 2020, 11, 1774 DOI: 10.1039/C9PY01654F

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