Issue 21, 2020

Rh(i)-Catalyzed regioselective arylcarboxylation of acrylamides with arylboronic acids and CO2

Abstract

The first Rh(I)-catalyzed regioselective arylcarboxylation of electron-deficient acrylamides with arylboronic acids under atmospheric pressure of CO2 has been developed. A range of acrylamides and arylboronic acids were compatible with this reaction under redox-neutral conditions, leading to a series of malonate derivatives that are versatile building blocks in organic syntheses.

Graphical abstract: Rh(i)-Catalyzed regioselective arylcarboxylation of acrylamides with arylboronic acids and CO2

Supplementary files

Article information

Article type
Communication
Submitted
03 aug 2020
Accepted
24 sep 2020
First published
24 sep 2020

Green Chem., 2020,22, 7328-7332

Rh(I)-Catalyzed regioselective arylcarboxylation of acrylamides with arylboronic acids and CO2

L. Cai, L. Fu, C. Zhou, Y. Gao, S. Li and G. Li, Green Chem., 2020, 22, 7328 DOI: 10.1039/D0GC02667K

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