Issue 12, 2020

A general and green fluoroalkylation reaction promoted via noncovalent interactions between acetone and fluoroalkyl iodides

Abstract

The first example of visible light promoted fluoroalkylation reactions initiated via noncovalent interactions between acetone and fluoroalkyl iodides is presented. The reaction system features synthetic simplicity, mild reaction conditions without any photoredox catalyst, and high functional group tolerance. A wide range of substrate scopes such as alkenes, alkynes and (hetero)arenes were all compatible with the reaction system.

Graphical abstract: A general and green fluoroalkylation reaction promoted via noncovalent interactions between acetone and fluoroalkyl iodides

Supplementary files

Article information

Article type
Communication
Submitted
07 dec 2019
Accepted
09 jan 2020
First published
09 jan 2020

Chem. Commun., 2020,56, 1815-1818

A general and green fluoroalkylation reaction promoted via noncovalent interactions between acetone and fluoroalkyl iodides

T. Mao, M. Ma, L. Zhao, D. Xue, Y. Yu, J. Gu and C. He, Chem. Commun., 2020, 56, 1815 DOI: 10.1039/C9CC09517A

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