Issue 41, 2019

A facile synthetic approach to nanostructured Li2S cathodes for rechargeable solid-state Li–S batteries

Abstract

Li–S solid state batteries, employing Li2S as a pre-lithiated cathode, present a promising low cost, high capacity and safer alternative to their liquid electrolyte counterparts, where dissolution of intermediate polysulfide species can result in loss of active material and a subsequent decrease in ionic conductivity. A nanostructured Li2S material would afford greater flexibility in optimising the cathode composite for more harmonious electrode–electrolyte interactions, yet facile routes to such nanoscale materials are limited. Here, we report a facile and scalable microwave approach to directly synthesize nanostructured Li2S from a glyme solution containing lithium polysulfides. As-synthesized Li2S presents an ideal architecture for the construction of free-standing cathodes for all-solid-state Li–S batteries.

Graphical abstract: A facile synthetic approach to nanostructured Li2S cathodes for rechargeable solid-state Li–S batteries

Supplementary files

Article information

Article type
Communication
Submitted
22 jul 2019
Accepted
09 sep 2019
First published
17 okt 2019
This article is Open Access
Creative Commons BY license

Nanoscale, 2019,11, 19297-19300

A facile synthetic approach to nanostructured Li2S cathodes for rechargeable solid-state Li–S batteries

H. El-Shinawi, E. J. Cussen and S. A. Corr, Nanoscale, 2019, 11, 19297 DOI: 10.1039/C9NR06239D

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements