Issue 18, 2019

Thulium doped LaF3 for nanothermometry operating over 1000 nm

Abstract

The use and applications of infrared emitting rare-earth luminescent nanoparticles as nanothermometers have attracted a great deal of attention during the last few years. Researchers have regarded rare-earth doped luminescent nanoparticles as appealing systems due to their reliability, sensitivity and versatility for minimally invasive thermal sensing in nanomedicine. The challenge of developing nanothermometers operating over 1000 nm with outstanding brightness and enhanced sensitivity is being constantly addressed. In this sense, this work explores the potential of Tm3+ emissions at around 1.23 and 1.47 μm, under excitation at 690 nm, for ratiometric thermometry in Tm3+ doped LaF3 nanoparticles. The temperature dependence of the 1.23 μm emission band, which cannot be observed in systems such as NaNbO3:Tm, was demonstrated to be very effective and presented a relative thermal sensitivity as high as 1.9% °C−1. The physical mechanisms behind the strong thermal dependences were explained in terms of multiphonon decays and cross-relaxations. As a proof of concept, the nanothermometers presented were capable of accessing the basic properties of tissues in an ex vivo experiment using thermal relaxation dynamics.

Graphical abstract: Thulium doped LaF3 for nanothermometry operating over 1000 nm

Supplementary files

Article information

Article type
Paper
Submitted
03 jan 2019
Accepted
04 apr 2019
First published
23 apr 2019

Nanoscale, 2019,11, 8864-8869

Thulium doped LaF3 for nanothermometry operating over 1000 nm

E. C. Ximendes, A. F. Pereira, U. Rocha, W. F. Silva, D. Jaque and C. Jacinto, Nanoscale, 2019, 11, 8864 DOI: 10.1039/C9NR00082H

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