Issue 62, 2017

A luminescent metal–organic framework as an ideal chemosensor for nitroaromatic compounds

Abstract

A luminescent two-dimensional metal–organic framework, [(Pr2(TATMA)2)·4DMF·4H2O]n (1), was solvothermally synthesized based on the semi-rigid organic ligand 4,4′,4′′-s-triazine-1,3,5-triyltri-m-aminobenzoate (H3TATMA). 1 possesses binuclear {Pr2(COO)6} subunits and fully deprotonated TATMA3− organic ligands, which can be further simplified into a 3,6-connected kgd topology with the Schläfli symbol of (43)2(46·66·83). More importantly, 1 displays fast and reversible solid-state detection of nitroaromatic compounds, especially for TNP, via a luminescence response.

Graphical abstract: A luminescent metal–organic framework as an ideal chemosensor for nitroaromatic compounds

Supplementary files

Article information

Article type
Paper
Submitted
06 jun 2017
Accepted
26 jul 2017
First published
08 aug 2017
This article is Open Access
Creative Commons BY license

RSC Adv., 2017,7, 38871-38876

A luminescent metal–organic framework as an ideal chemosensor for nitroaromatic compounds

H. He, S. Chen, D. Zhang, E. Yang and X. Zhao, RSC Adv., 2017, 7, 38871 DOI: 10.1039/C7RA06320B

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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