Issue 14, 2016

Smallest molecular chalcogenidometalate anions of the heaviest metals: syntheses, structures, and their interconversion

Abstract

The syntheses of the first molecular meta-selenidomercurate(II), ortho-telluridothallate(III) and a hydrate of an ortho-selenidoplubate(IV) are presented alongside an improved and facile synthesis of the selenidobismuthate(III) with almost quantitative yields. By means of quantum chemical calculations, the energetics of the interconversions of small metalate anions is discussed and the existence of the heaviest homologues of [NO2], [NO3], [PO4]2− and [CO3]2− are predicted.

Graphical abstract: Smallest molecular chalcogenidometalate anions of the heaviest metals: syntheses, structures, and their interconversion

Supplementary files

Article information

Article type
Paper
Submitted
12 okt 2015
Accepted
30 okt 2015
First published
16 nov 2015
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2016,45, 5958-5967

Author version available

Smallest molecular chalcogenidometalate anions of the heaviest metals: syntheses, structures, and their interconversion

G. Thiele, C. Donsbach, R. Riedel, M. Marsch, K. Harms and S. Dehnen, Dalton Trans., 2016, 45, 5958 DOI: 10.1039/C5DT03996G

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